Single-molecule magnets (SMMs) are molecules that exhibit energy barriers to spin
inversion. The slow relaxation of magnetization is of molecular origin and arises from the …

Novel ligand platforms that promote reactivity are of long standing and continued interest in
coordination chemistry, with Schiff base ligands and their metal complexes representing one …

Single-molecule magnets (SMMs) that contain one spin centre (so-called single-ion
magnets) theoretically represent the smallest possible unit for spin-based electronic devices …

One of the determining factors in whether single-molecule magnets (SMMs) may be used as
the smallest component of data storage, is the size of the barrier to reversal of the …

Abstract Single‐ion magnets (SIMs), exhibiting slow magnetization relaxation in the absence
of the magnetic field, originate from their single spin‐carrier centre. In pursuit of high …

Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …

This review considers the most recent experimental developments in the magnetic
anisotropy of mono-nuclear transition metal complexes in various coordination …

Single-molecule magnets that contain one spin centre may represent the smallest possible
unit for spin-based computational devices. Such applications, however, require the …

This review examines mononuclear metal complexes with high magnetic anisotropy and the
theoretical approaches used to rationalize their magnetic properties. Electronic structure …

Magnetic anisotropy is the property that confers to the spin a preferred direction that could
be not aligned with an external magnetic field. Molecules that exhibit a high degree of …