The production of hydrogen through water splitting using earth-abundant metal catalysts is a
promising pathway for converting solar energy into chemical fuels. However, existing …

Despite the proliferation of tungstate and molybdate polyoxometalates (POMs) the inclusion
of sulfides into these structures proved to be challenging. The use of appropriate preformed …

The catalytic efficacy of a novel mononuclear rhenium (I) complex in CO2 reduction is
remarkable, with a turnover number (TONCO) of 1517 in 3 h, significantly outperforming …

The assembly of [Mo2O2S2] 2+ units depends on the configuration of polydentate
phosphonic acid templates, leading to novel topologies with enhanced nuclearity and …

Reaction of the cyclic ligand (2Z, 6Z)-piperidine-2, 6-dione dioxime with TiCl4 and KOH
yielded the hexanuclear cluster K6 [TiIV6 (μ3-O) 2 (μ2-O) 3 (CH3O) 6 (μ2–η1, η1, η2 …

The chelating catechol/oxime ligand 2, 3-dihydroxybenzaldehyde oxime (H3dihybo) has
been used to synthesize one titanium (IV) and two zirconium (IV) compounds that have been …

Phosphoester hydrolysis is an important chemical step in DNA repair. One archetypal
molecular model of phosphoesters is para‐nitrophenylphosphate (pNPP). It has been …

The activation of dioxygen by metal ions is critical in chemical and bio-chemical processes.
A scientific challenge is the elucidation of the activation site of dioxygen in some copper …

Mixed‐valent polyoxometalate (POM) clusters are one of the most interesting host species,
showing a wide range of structural features and properties. The facile preparation and …

Three cyclic polyoxothiomolybdates [Mo20O20S20 (OH) 20 (PyD) 2] 4−(1)(PyD2−= 3, 5-
pyridinedicarboxylic acid, C7H6O4N2−),[Mo12O12S12 (OH) 12 (H2O) 5 (NapH)] …