[HTML][HTML] Composites and Materials Prepared from Boron Cluster Anions and Carboranes

VV Avdeeva, SE Nikiforova, EA Malinina, IB Sivaev… - Materials, 2023 - mdpi.com
Here, we present composites and materials that can be prepared starting with boron hydride
cluster compounds (decaborane, decahydro-closo-decaborate and dodecahydro-closo …

[HTML][HTML] Chemistry of Carbon-Substituted Derivatives of Cobalt Bis(dicarbollide)(1) Ion and Recent Progress in Boron Substitution

L Pazderová, EZ Tüzün, D Bavol, M Litecká, L Fojt… - Molecules, 2023 - mdpi.com
The cobalt bis (dicarbollide)(1−) anion (1−),[(1, 2-C2B9H11) 2-3, 3′-Co (III)](1−), plays an
increasingly important role in material science and medicine due to its high chemical …

Visible‐Light‐Induced Photoreduction of Carborane Phosphonium Salts: Efficient Synthesis of Carborane‐Oxindole‐Pharmaceutical Hybrids

Q Liu, BB Zhang, H Sheng, S Qiao… - Angewandte …, 2023 - Wiley Online Library
Visible‐light‐induced photoreaction of carboranes is an effective approach to prepare
carborane‐containing compounds. While several methods involving boron‐centered …

Visible-Light-Promoted Nickel-Catalyzed Cross-Coupling of Iodocarboranes with (Hetero) Arenes via Boron-Centered Carboranyl Radicals

S Li, Z Xie - Journal of the American Chemical Society, 2022 - ACS Publications
A general strategy for the generation of hypervalent boron-centered carboranyl radicals at
the B (3), B (4), and B (9) positions has been developed for the first time via visible-light …

[HTML][HTML] Boron clusters as enhancers of RNase H activity in the smart strategy of gene silencing by antisense oligonucleotides

D Kaniowski, K Kulik, J Suwara… - International Journal of …, 2022 - mdpi.com
Boron cluster-conjugated antisense oligonucleotides (B-ASOs) have already been
developed as therapeutic agents with “two faces”, namely as potential antisense inhibitors of …

[HTML][HTML] Exploiting blood transport proteins as carborane supramolecular vehicles for boron neutron capture therapy

TD Marforio, EJ Mattioli, F Zerbetto, M Calvaresi - Nanomaterials, 2023 - mdpi.com
Carboranes are promising agents for applications in boron neutron capture therapy (BNCT),
but their hydrophobicity prevents their use in physiological environments. Here, by using …

Charge Transfer Complex-Enabled Synthesis of (Hetero)arylated m-Carboranes from m-Carborane Phosphonium Salts

QS Zhang, L He, Q Liu, XY Chen - Organic Letters, 2023 - ACS Publications
A photoinduced charge transfer complex (CTC)-enabled photoreduction of carborane
phosphonium salts for the cage carbon (hetero) arylation of carboranes was developed. It …

[HTML][HTML] Carborane-Containing Folic Acid bis-Amides: Synthesis and In Vitro Evaluation of Novel Promising Agents for Boron Delivery to Tumour Cells

DA Gruzdev, AA Telegina, GL Levit… - International Journal of …, 2022 - mdpi.com
The design of highly selective low-toxic, low-molecular weight agents for boron delivery to
tumour cells is of decisive importance for the development of boron neutron capture therapy …

New nido-carborane-containing conjugates of purine: synthesis and antiviral activity

DA Gruzdev, AA Telegina, VA Ol'shevskaya… - Russian Chemical …, 2022 - Springer
New purine derivatives containing a nido-carborane fragment were synthesized by
nucleophilic substitution of chlorine atom in 6-chloropurine and 2-amino-6-chloropurine …

[HTML][HTML] EGFR-targeted cellular delivery of therapeutic nucleic acids mediated by boron clusters

D Kaniowski, J Suwara, K Ebenryter-Olbińska… - International Journal of …, 2022 - mdpi.com
New boron carriers with high boron content and targeted cancer-cell delivery are considered
the first choice for boron neutron capture therapy (BNCT) for cancer treatment. Previously …