Potential and challenges of engineering mechanically flexible molecular crystals

A Hasija, D Chopra - CrystEngComm, 2021 - pubs.rsc.org
This highlight gives an overview of recent advances in mechanically flexible molecular
crystals, with qualitative and quantitative studies performed on different molecular systems …

Elastic Crystalline Fibers Composed of a Nickel (II) Complex

S Kusumoto, A Sugimoto, Y Zhang, Y Kim… - Inorganic …, 2021 - ACS Publications
The generation of elastic crystalline fibers from a nonfibrous crystal of metal complex is
demonstrated. Applying mechanical stimuli to a platelike crystal of NiII (salophen)[1; …

Diverse Mechanical Properties of 1, 3-Bis (4-nitrophenyl) thiourea–DMSO Dimorphic Solvates

A Hasija, S Bhandary, SRNK Mangalampalli… - Crystal Growth & …, 2022 - ACS Publications
The distinct mechanical properties of concomitant dimorphs (Form α and Form β) of 1, 3-bis
(4-nitrophenyl) thiourea–DMSO solvate (TU-DMSO) have been investigated via …

Modulation of the elasticity of single crystal, 1-D metal dimethylglyoximato complexes via solid solution effect

A Sugimoto, S Kusumoto, M Nakaya, Y Sekine… - …, 2022 - pubs.rsc.org
The fabrication of single crystal material with a desired degree of flexibility is a challenging
topic in material science and crystal engineering. In this communication, we demonstrate the …

Elastic deformability and luminescence of crystals of polyhalogenated platinum (II)–bipyridine complexes

M Yoshida, Y Makino, T Sasaki, S Sakamoto… - …, 2021 - pubs.rsc.org
Single crystals showing elastic flexibility have attracted increasing attention as next-
generation soft materials. Herein, we successfully developed a series of polyhalogenated …

Multi-faceted elastic flexibility of 1-naphthyl and 9-anthryl 2, 2′: 6′, 2′′-terpyridine crystals

S Kusumoto, K Oishi, M Nakaya, R Suzuki… - …, 2022 - pubs.rsc.org
Functional molecular crystals capable of multidirectional deformation by external stimuli
have the potential to be used in various applications such as mechanosensors and flexible …

Crystal Design for Tuning the Mechanical Flexibilities of M (salophen) Complexes

Y Sekine, S Kusumoto, A Sugimoto… - Crystal Growth & …, 2023 - ACS Publications
Elastic crystals are a novel class of materials for use in optoelectronics and solar cells.
Although controlling mechanical flexibility is critical when developing functional soft crystals …

A plastically bendable and polar organic crystal

S Kusumoto, A Sugimoto, D Kosumi, Y Kim, Y Sekine… - …, 2021 - pubs.rsc.org
In this communication, an organic crystal of the polar space group Pc that is capable of
plastic bending in response to external mechanical stress is reported, and its high dielectric …

Probing the distinct nanomechanical behaviour of a new co-crystal and a known solvate of 5-fluoroisatin and identification of a new polymorph

PK Mondal, S Bhandary, MG Javoor, A Cleetus… - …, 2020 - pubs.rsc.org
New crystalline forms (a polymorph and a co-crystal) and a previously reported solvate of
the parent compound 5-fluoroisatin have been characterized by thermal, structural, and …