Hypervalent iodine (III) compounds have found wide application in modern organic
chemistry as environmentally friendly reagents and catalysts. Hypervalent iodine reagents …

The site-selective C–H bond functionalization of heteroarenes can eventually provide
chemists with great techniques for editing and building complex molecular scaffolds. During …

Conspectus The widespread presence of hydrocarbons makes C–H functionalization an
attractive alternative to traditional cross-coupling methods. As indole is an important …

Transition-metal catalyzed C–H activation reactions have been proven to be useful
methodologies for the assembly of synthetically meaningful molecules. This approach bears …

Indole is one of the most important heterocycles in organic synthesis, natural products, and
drug discovery. Recently, tremendous advances in the selective functionalization of indoles …

Over the last two decades, transition-metal catalyzed C–H functionalization of indoles has
emerged as an area of extensive research and tremendous progress has been made in this …

Rhodium (III)-catalyzed C–H activation-based arylation of sterically hindered (hetero) arenes
has been realized using diazo compounds and triazoles as arylating reagents for …

Herein, we report the additive-controlled divergent synthesis of tetrasubstituted 1, 3-enynes
and alkynylated 3 H-pyrrolo [1, 2-a] indol-3-ones through rhodium-catalyzed C–H …

Transition metal‐catalyzed C− H activation is a step‐economical strategy for peptide
functionalization. Herein, we report the method of late‐stage peptide ligation and …

Efficient C4-arylation and domino C4-arylation/3, 2-carbonyl migration of indoles have been
developed. The former route enables C4-arylation in a highly efficient and mild manner and …