Field-induced slow magnetic relaxation in a six-coordinate mononuclear cobalt (II) complex with a positive anisotropy

J Vallejo, I Castro, R Ruiz-García, J Cano… - Journal of the …, 2012 - ACS Publications
The novel mononuclear Co (II) complex cis-[CoII (dmphen) 2 (NCS) 2]· 0.25 EtOH
(1)(dmphen= 2, 9-dimethyl-1, 10-phenanthroline) features a highly rhombically distorted …

Magnetic properties of six-coordinated high-spin cobalt (II) complexes: Theoretical background and its application

F Lloret, M Julve, J Cano, R Ruiz-García… - Inorganica Chimica Acta, 2008 - Elsevier
In this contribution we study and analyse the influence of the different parameters involved in
the magnetic susceptibility of six-coordinated high-spin Co (II) complexes. We propose an …

The variable coordination chemistry of a potentially heptadentate ligand with a series of 3d transition metal ions. The chemistry and structures of [M (py3tren)] 2+ …

RM Kirchner, C Mealli, M Bailey, N Howe… - Coordination Chemistry …, 1987 - Elsevier
Transition metal complexes with a multidentate chelating ligand can exhibit “special”
physical, chemical or structural properties such as (1) unusual conformation,(2) extremely …

Cyano-Bridged Re6Q8 (Q = S, Se) Cluster-Cobalt(II) Framework Materials:  Versatile Solid Chemical Sensors

LG Beauvais, MP Shores, JR Long - Journal of the American …, 2000 - ACS Publications
Face-capped octahedral clusters of the type [Re6Q8 (CN) 6] 4-(Q= S, Se) are used to space
apart partially hydrated Co2+ ions in extended solid frameworks, creating porous materials …

Some considerations on the proper use of computational tools in transition metal chemistry

A Bencini - Inorganica Chimica Acta, 2008 - Elsevier
Some considerations on the proper use of computational tools in transition metal chemistry -
ScienceDirect Skip to main contentSkip to article Elsevier logo Journals & Books Search …

Synthesis, Structure and Magnetism of Homologous Series of Polycrystalline Cobalt Alkane Mono‐and Dicarboxylate Soaps

JM Rueff, N Masciocchi, P Rabu… - … A European Journal, 2002 - Wiley Online Library
Carboxylate‐bridged chain complexes of CoII (the diaquacobalt (ii) mono‐and α, ω‐
dialkanoates) form two homologous series of layered compounds which have been fully …

Guest-dependent single-ion magnet behaviour in a cobalt (II) metal–organic framework

J Vallejo, FR Fortea-Pérez, E Pardo, S Benmansour… - Chemical …, 2016 - pubs.rsc.org
Single-ion magnets (SIMs) are the smallest possible magnetic devices for potential
applications in quantum computing and high-density information storage. Both, their …

Structure and Magnetism of a Polycrystalline Transition Metal Soap − CoII[OOC(CH2)10COO](H2O)2

JM Rueff, N Masciocchi, P Rabu… - European Journal of …, 2001 - Wiley Online Library
Abstract Diaquacobalt (II) n‐dodecane‐α, ω‐dioate (2) has been synthesized by metathesis
of the corresponding potassium soap 1 and has been fully characterized by chemical and …

Crystal structures and magnetic properties of two octacyanotungstate (IV) and (V)-cobalt (II) three-dimensional bimetallic frameworks

JM Herrera, A Bleuzen, Y Dromzée, M Julve… - Inorganic …, 2003 - ACS Publications
The synthesis, X-ray structures, and magnetic behavior of two new, three-dimensional
compounds [WIV {(μ-CN) 4CoII (H2O) 2} 2⊙ 4H2O] n (1) and [{WV (CN) 2} 2 {(μ-CN) 4CoII …

Magneto-Structural Correlations in Pseudotetrahedral Forms of the [Co(SPh)4]2– Complex Probed by Magnetometry, MCD Spectroscopy, Advanced EPR …

EA Suturina, J Nehrkorn, JM Zadrozny, J Liu… - Inorganic …, 2017 - ACS Publications
The magnetic properties of pseudotetrahedral Co (II) complexes spawned intense interest
after (PPh4) 2 [Co (SPh) 4] was shown to be the first mononuclear transition-metal complex …