Metathesis by Partner Interchange in σ‐Bond Ligands: Expanding Applications of the σ‐CAM Mechanism

RN Perutz, S Sabo‐Etienne… - Angewandte Chemie …, 2022 - Wiley Online Library
In 2007 two of us defined the σ‐Complex Assisted Metathesis mechanism (Perutz and Sabo‐
Etienne, Angew. Chem. Int. Ed. 2007, 46, 2578–2592), that is, the σ‐CAM concept. This new …

A Series of Crystallographically Characterized Linear and Branched σ-Alkane Complexes of Rhodium: From Propane to 3-Methylpentane

AJ Bukvic, AL Burnage, GJ Tizzard… - Journal of the …, 2021 - ACS Publications
Using solid-state molecular organometallic (SMOM) techniques, in particular solid/gas
single-crystal to single-crystal reactivity, a series of σ-alkane complexes of the general …

In crystallo lattice adaptivity triggered by solid-gas reactions of cationic group 7 pincer complexes

JC Goodall, MA Sajjad, EA Thompson… - Chemical …, 2023 - pubs.rsc.org
The group 7 complexes [M (κ3-2, 6-(R2PO) 2C5H3N)(CO) 2L][BArF4][M= Mn, R= iPr, L=
THF; M= Re, R= tBu, L= vacant site] undergo in crystallo solid-gas reactivity with CO to form …

Inverse isotope effects in single-crystal to single-crystal reactivity and the isolation of a rhodium cyclooctane σ-alkane complex

LR Doyle, MR Galpin, SK Furfari, BE Tegner… - …, 2022 - ACS Publications
The sequential solid/gas single-crystal to single-crystal reaction of [Rh (Cy2P (CH2)
3PCy2)(COD)][BArF4](COD= cyclooctadiene) with H2 or D2 was followed in situ by solid …

[图书][B] Annual reports on NMR spectroscopy

WS Price - 2024 - books.google.com
Annual Reports on NMR Spectroscopy, Volume 111 presents the latest release in a series
that has established itself as a premier resource for both specialists and non-specialists …

A comparison of non-covalent interactions in the crystal structures of two σ-alkane complexes of Rh exhibiting contrasting stabilities in the solid state

MA Sajjad, SA Macgregor, AS Weller - Faraday Discussions, 2023 - pubs.rsc.org
Non-covalent interactions surrounding the cationic Rh σ-alkane complexes within the crystal
structures of [(Cy2PCH2CH2PCy2) Rh (NBA)][BArF4],[1-NBA][BArF4](NBA= norbornane …

Solid‐State Confinement Effects in Selective exo‐H/D Exchange in the Rhodium σ‐Norbornane Complex [(Cy2PCH2CH2PCy2)Rh(η22‐C7H12)][BArF4 …

T Krämer, FM Chadwick, SA Macgregor… - Helvetica Chimica …, 2023 - Wiley Online Library
Density functional theory calculations modelling selective exo‐H/D exchange observed in
the Rh σ‐alkane complex [(Cy2PCH2CH2PCy2) Rh (η2: η2‐endo‐NBA)][BArF4],[1 …

Ortho‐F,F‐DPEphos: Synthesis and Coordination Chemistry in Rhodium and Gold Complexes, and Comparison with DPEphos

JJ Race, MJ Webb, T Morgan Boyd… - European Journal of …, 2022 - Wiley Online Library
The synthesis of a new ortho‐fluorine substituted diphosphine ligand based upon the
DPEphos ligand is reported: o‐F, F‐DPEphos (DPEphos= bis (2‐diphenylphosphinophenyl) …

[PDF][PDF] Using Catalysts with ZSM-48 Zeolite Support and MOF-5 Organic-Metallic Framework in the Oxidative Dehydrogenation Process of Propane to Produce …

AH Shahbazi Kootenaei, M Narimani - Iran. J. Chem. Chem. Eng.(IJCCE) …, 2024 - ijcce.ac.ir
In this research, catalysts with zeolite bases ZSM-48 and organic-metallic framework MOF-5
were used as catalytic bases in the process of oxidative dehydrogenation of propane to …

A New Method for the Synthesis of Cr-V@ MOF5 Catalyst Regarding the Investigation of the Simultaneous Effect of Effective Parameters in the Oxidative …

SH Shafeianpour, A Borsalani… - Iranian Journal of …, 2024 - ijcce.ac.ir
This research study utilized the synthesis method of the Cr-V@ MOF5 catalyst to integrate
findings from multiple prior studies. The oxidative dehydrogenation method was chosen due …