This Review compiles the evolution, mechanistic understanding, and more recent advances
in enantioselective Pd-catalyzed allylic substitution and decarboxylative and oxidative allylic …

Synergistic catalysis is gaining increasing attention due to its advantages over traditional
catalytic methodologies, such as improved catalytic activity, broader substrate scope …

Catalytic asymmetric cycloadditions of reactive ketene intermediates provide new
opportunities for the production of chiral heterocyclic molecules. Though known for over 100 …

We report a stereoselective and site-specific allylic alkylation of Schiff base activated amino
acids and small peptides via a Pd/Cu dual catalysis. A range of noncoded α, α-dialkyl α …

A palladium-catalyzed enantioselective α-allylation of deconjugated butenolides with aza-π-
allylpalladium 1, 4-diploes, in situ generated from palladium-mediated decarboxylation of …

Inspired by a fungicide, we designed 5-vinyloxazolidine-2, 4-diones as new precursors of π-
allylpalladium zwitterionic intermediates and developed palladium-catalyzed asymmetric …

Dipolar cycloaddition is one of the most valuable methods for synthesizing various carbo-
and heterocycles because multiple carbon–carbon and carbon–heteroatom bonds form in a …

Abstract Higher‐order cycloadditions, particularly [8+ 2] cycloadditions, are a straightforward
and efficient strategy for constructing significant medium‐sized architectures. Typically …

Palladium-catalyzed cycloaddition reactions via Pd-π-allyl zwitterions have been
established as significant synthetic transformations to enable numerous carbon-or …

The nine-membered ring-bearing bicyclo [5.2. 2] tetrahydrooxonines frameworks have
enantioselectively been constructed via a tandem [3+ 2] cycloaddition/Cope rearrangement …