Methods of nitriles synthesis from amines through oxidative dehydrogenation

RD Patil, MK Gupta - Advanced Synthesis & Catalysis, 2020 - Wiley Online Library
In recent years, oxidative dehydrogenation (ODH) of amines has proven to be an efficient,
clean and fundamental route for the synthesis of nitriles. This review focuses on the different …

Innovative green oxidation of amines to imines under atmospheric oxygen

Y Yamamoto, S Kodama, A Nomoto… - Organic & Biomolecular …, 2022 - pubs.rsc.org
In recent years, the development of environmentally benign molecular construction methods
has been of great importance, and especially, resource recycling, high atomic efficiency, and …

Ruthenium-Catalyzed C–F Bond Arylation of Polyfluoroarenes: Polyfluorinated Biaryls by Integrated C–F/C–H Functionalization

J Zhang, J Liu, X Wang, X Yang, Y Ma, R Fang… - ACS …, 2022 - ACS Publications
Fluorine-containing molecules are central motifs in pharmaceuticals, agrochemicals, and
functional materials owing to the unique properties engendered by carbon–fluorine bonds …

Cercosporin-bioinspired selective photooxidation reactions under mild conditions

J Li, W Bao, Z Tang, B Guo, S Zhang, H Liu… - Green …, 2019 - pubs.rsc.org
The development of an efficient system for selective oxidation of organic compounds to
generate more valuable compounds with molecular oxygen is a significant challenge in …

Designed pincer ligand supported Co (II)-based catalysts for dehydrogenative activation of alcohols: Studies on N-alkylation of amines, α-alkylation of ketones and …

A Singh, A Maji, M Joshi, AR Choudhury… - Dalton Transactions, 2021 - pubs.rsc.org
Base-metal catalysts Co1, Co2 and Co3 were synthesized from designed pincer ligands L1,
L2 and L3 having NNN donor atoms respectively. Co1, Co2 and Co3 were characterized by …

Metal–ligand synergy driven functionalisation of alkylene linked bis (aldimine) on a diruthenium (ii) platform. Cyclisation versus oxygenation

M Biswas, S Dey, S Dhara, S Panda, GK Lahiri - Dalton Transactions, 2024 - pubs.rsc.org
This article addresses the impact of metal–ligand redox cooperativity on the functionalisation
of coordinated ligands. It demonstrates the structure–reactivity correlation of bis (aldimine) …

Osmium hydride acetylacetonate complexes and their application in acceptorless dehydrogenative coupling of alcohols and amines and for the dehydrogenation of …

MA Esteruelas, V Lezáun, A Martínez, M Oliván… - …, 2017 - ACS Publications
The preparation of new osmium hydride complexes, starting from OsH6 (PiPr3) 2 (1) and
OsH2Cl2 (PiPr3) 2 (2), and their catalytic activity in acceptorless dehydrogenative coupling …

Aerobic oxidation of primary amines to imines in water using a cobalt complex as recyclable catalyst under mild conditions

S Hazra, P Pilania, M Deb… - … –A European Journal, 2018 - Wiley Online Library
Oxidative coupling of primary amines to imines has been achieved by using a water soluble
cobalt complex as catalyst and air as the oxidant at near ambient conditions. Aromatic …

Microporous cobaltporphyrin covalent polymer mediated Co3O4@ PNC nanocomposites for efficient catalytic CH bond activation

M Tan, L Zhu, H Liu, Y Fu, SF Yin, W Yang - Applied Catalysis A: General, 2021 - Elsevier
A Cobalt porphyrin conjugated porous polymer (Co/PCP) was obtained by hybrid
polymerization of a mixture of Co (II)(5, 10, 15, 20-tetrakis (4-bromophenyl)-21H, 23H …

Ruthenium‐catalyzed aerobic oxidation of amines

R Ray, AS Hazari, GK Lahiri… - Chemistry–An Asian …, 2018 - Wiley Online Library
Amine oxidation is one of the fundamental reactions in organic synthesis as it leads to a
variety of value‐added products such as oximes, nitriles, imines, and amides among many …