Electronic Profiling of N-Phosphine Oxide-Substituted Imidazolin-2-ylidenes (PoxIms) and Imidazolidin-2-ylidenes (SPoxIms)
JN Leung, Y Mondori, S Ogoshi, Y Hoshimoto… - Inorganic …, 2024 - ACS Publications
A detailed electronic study of the N-phosphine oxide functionalized imidazolin-2-ylidenes
(PoxIms) and imidazolidin-2-ylidenes (SPoxIms) has been performed experimentally using …
(PoxIms) and imidazolidin-2-ylidenes (SPoxIms) has been performed experimentally using …
Palladium catalyzed ortho-C(sp2)–H activation/cyclization of aryl amines assisted by imine and vinylacetic acid
X Tan, Y Jing, J Wu, J Li, Z Yang, W Wu, Z Ke… - Nature …, 2024 - nature.com
Palladium-catalyzed directed C− H functionalization/cyclization is an effective approach for
synthesizing nitrogen heterocycles. Imine, known for its ease of installation/removal, has …
synthesizing nitrogen heterocycles. Imine, known for its ease of installation/removal, has …
Revisiting Isomerism in Square Planar Palladium NHC Complexes with NacAc Chelators
Quantifying the donor ability of bidentate ligands in inorganic chemistry is not
straightforward, and the Huynh electronic parameter for chelators (HEP2) presents a rare …
straightforward, and the Huynh electronic parameter for chelators (HEP2) presents a rare …
Donor Strength Determination of Anionic Ligands
HV Huynh, JN Leung, TT Lam - Inorganic Chemistry, 2023 - ACS Publications
14 new gold (I) NHC complexes of the type [AuX (i Pr2-bimy)](i Pr2-bimy= 1, 3-
diisopropylbenzimidazolin-2-ylidene) have been prepared and fully characterized. These …
diisopropylbenzimidazolin-2-ylidene) have been prepared and fully characterized. These …
Stereoelectronic Profiling of Neutral and Monoanionic Biimidazoles and Mixed Diimines
JN Leung, HTT Luong, HV Huynh - Inorganic Chemistry, 2023 - ACS Publications
14 mono-, di-, and tetranuclear palladium complexes were prepared to study the
coordination chemistry of symmetrical and unsymmetrical azole-derived diimines and their …
coordination chemistry of symmetrical and unsymmetrical azole-derived diimines and their …
Modification of a Common β‐diketiminate NacNac Framework via Sequential Lithiation and Small Molecule Insertion
JR Lynch, AR Kennedy, J Barker… - Chemistry–A European …, 2024 - Wiley Online Library
A widely utilised class of ligands in synthesis and catalysis, β‐diketiminate (BDI) or NacNac
compounds were initially considered innocent in the sense that they remained intact in all …
compounds were initially considered innocent in the sense that they remained intact in all …
Expanding the library of β-ketoiminates via terminal alkylation of the backbone and their application to the synthesis of unsymmetric 2, 4-disubstituted quinolines
X Zhu, Z Kang, C Chen, Y Zheng, M Xue - Tetrahedron, 2025 - Elsevier
ABSTRACT β-Ketoiminates, as ligands and synthetic intermediates, have wide applications
in organometallic chemistry and organic synthesis. However, the modification of the terminal …
in organometallic chemistry and organic synthesis. However, the modification of the terminal …
Mixed N‐heterocyclic carbene and benzyl‐, phenethyl‐, and biphenylamine coordinated Pd complexes: Anticancer activities and stereo‐electronic effects
Q Teng, H Song, H Chen, E Sang… - Applied …, 2024 - Wiley Online Library
A series of mixed N‐heterocylic carbene (NHC) palladium complexes bearing C^ N
bidentate ligands derived from benzylamine, phenethylamine, and biphenylamine were …
bidentate ligands derived from benzylamine, phenethylamine, and biphenylamine were …
Palladium Catalyzed ortho-C (sp2)–H Activation/Cyclization of Aryl Amines Assisted by Imine Directing Group and Vinylacetic Acid
H Jiang, X Tan, Y Jing, J Wu, J Li - 2024 - researchsquare.com
Palladium-catalyzed directed C− H functionalization/cyclization is an effective approach for
synthesizing nitrogen heterocycles. Imine, known for its ease of installation/removal, has …
synthesizing nitrogen heterocycles. Imine, known for its ease of installation/removal, has …