Unlike natural macromolecules (eg, nucleic acids and proteins) possessing precisely
defined molar mass, chain sequence, chirality, and topology, synthetic polymers are typically …

Natural macromolecules, such as proteins and nucleic acids, display various complex
functionalities in biological systems. These functionalities depend on the macromolecular …

In the last decade, the field of sequence‐defined polymers and related ultraprecise,
monodisperse synthetic macromolecules has grown exponentially. In the early stage, mainly …

Precise sequence‐defined polymers (SDPs) with uniform chain‐to‐chain structure including
chain length, unit sequence, and end functionalities represent the pinnacle of sophistication …

High-yielding and scalable methods for iterative synthesis of sequence-defined
macromolecules are a great challenge in modern polymer chemistry. Sequence-defined …

Nitroxide-mediated catalytic systems have been widely used for selective oxidation with
superior catalytic performance. From economic and environmental points of view …

We show the emergence of strong catalytic activity at low concentrations in dynamic libraries
of complementary sequence-defined oligomeric chains comprising pendant functional …

Discrete sequence-defined oligomers are synthetic mimics of short peptides, with possible
applications in catalysis, information storage, drug delivery or self-assembly. Here, we report …

Similar to biological macromolecules such as DNA and proteins, the precise control over the
monomer position in sequence-defined polymers is of paramount importance for tuning their …

The development of precision polymer synthesis has facilitated access to a diverse library of
abiotic structures wherein chiral monomers are positioned at specific locations within …