Challenges and opportunities: Metal–organic frameworks for direct air capture

S Bose, D Sengupta, TM Rayder… - Advanced Functional …, 2023 - Wiley Online Library
Global reliance on fossil fuel combustion for energy production has contributed to the rising
concentration of atmospheric CO2, creating significant global climate challenges. In this …

Tuning Reactive Crystallization Pathways for Integrated CO2 Capture, Conversion, and Storage via Mineralization

P Ochonma, X Gao, G Gadikota - Accounts of Chemical Research, 2024 - ACS Publications
Conspectus Achieving carbon neutrality requires realizing scalable advances in energy-and
material-efficient pathways to capture, convert, store, and remove anthropogenic CO2 …

Tuning sorbent properties to reduce the cost of direct air capture

HE Holmes, S Banerjee, A Vallace, RP Lively… - Energy & …, 2024 - pubs.rsc.org
The question has shifted from whether solid sorbents can work in direct air capture (DAC)
technologies to which solid sorbents are more economically advantaged. Determining this is …

Tailoring Hydrophobicity and Pore Environment in Physisorbents for Improved Carbon Dioxide Capture under High Humidity

X Wang, M Alzayer, AJ Shih, S Bose… - Journal of the …, 2024 - ACS Publications
CALF-20, a Zn-triazolate-based metal–organic framework (MOF), is one of the most
promising adsorbent materials for CO2 capture. However, competitive adsorption of water …

Metal–Organic Framework Stability in Water and Harsh Environments from Data-Driven Models Trained on the Diverse WS24 Data Set

GG Terrones, SP Huang, MP Rivera… - Journal of the …, 2024 - ACS Publications
Metal–organic frameworks (MOFs) are porous materials with applications in gas separations
and catalysis, but a lack of water stability often limits their practical use given the ubiquity of …

The role of terminal coordinated amides in a series of Ca-tatb frameworks: pore size regulation and fluorescence sensing tunability

B Tan, XZ Hei, YP Lin, ZF Wu, XY Huang - Journal of Materials …, 2023 - pubs.rsc.org
Pore size tunability is of great importance to porous materials with applications in sieving
adsorption, barrier separation, stereospecific catalysis, and so forth. In this work, we present …

Development of a Multiparticulate Metal–Organic Framework/Textile Fiber Swatch

S Bose, D Sengupta, X Wang, CS Smoljan… - … Applied Materials & …, 2024 - ACS Publications
The versatility of metal–organic frameworks (MOFs) has led to groundbreaking applications
in a wide variety of fields, especially in the areas of energy, environment, and sustainability …

Integrated CO2 Capture and Conversion by a Robust Cu(I)-Based Metal–Organic Framework

D Sengupta, S Bose, X Wang… - Journal of the …, 2024 - ACS Publications
Metal–organic frameworks (MOFs) have shown promise in both capturing CO2 under flue
gas conditions and converting it into valuable chemicals. However, the development of a …

Recent advances, challenges, and perspectives on carbon capture

S Zhang, Y Shen, C Zheng, Q Xu, Y Sun… - … Science & Engineering, 2024 - Springer
Carbon capture, utilization and storage (CCUS) technologies play an essential role in
achieving Net Zero Emissions targets. Considering the lack of timely reviews on the recent …

Halogen-Decorated Metal–Organic Frameworks for Efficient and Selective CO2 Capture, Separation, and Chemical Fixation with Epoxides under Mild Conditions

A Karmakar, AACD Santos, N Pagliaricci… - … Applied Materials & …, 2024 - ACS Publications
In the present work, three novel halogen-appended cadmium (II) metal–organic frameworks
[Cd2 (L1) 2 (4, 4′-Bipy) 2] n· 4 n (DMF)(1),[Cd2 (L2) 2 (4, 4′-Bipy) 2] n· 3 n (DMF)(2), and …