The interaction of water with solid surfaces: fundamental aspects revisited

MA Henderson - Surface Science Reports, 2002 - Elsevier
Water is perhaps the most important and most pervasive chemical on our planet. The
influence of water permeates virtually all areas of biochemical, chemical and physical …

Recent advances in the molecular-level understanding of catalytic hydrogenation and oxidation reactions at metal-aqueous interfaces

Y Gu, L Wang, BQ Xu, H Shi - Chinese Journal of Catalysis, 2023 - Elsevier
Solid-aqueous interfaces and their associated phenomena (adsorption, nucleation,
corrosion, catalysis, etc.) are ubiquitous in a multitude of chemical systems linking various …

Kinetic significance of proton–electron transfer during condensed phase reduction of carbonyls on transition metal clusters

J Shangguan, YHC Chin - ACS Catalysis, 2019 - ACS Publications
Kinetic measurements, competitive hydrogenation, and H–D kinetic isotopic studies confirm
the prevalence of proton–electron transfer events during the catalytic reduction of aliphatic …

Mechanistic study of the electrochemical oxygen reduction reaction on Pt (111) using density functional theory

MP Hyman, JW Medlin - The Journal of Physical Chemistry B, 2006 - ACS Publications
Density functional theory (DFT) was used to study the electrolyte solution effects on the
oxygen reduction reaction (ORR) on Pt (111). To model the acid electrolyte, an H5O2+ …

Promotion and poisoning of the reaction of methanol on clean and modified platinum (100)

N Kizhakevariam, EM Stuve - Surface science, 1993 - Elsevier
The reactivity of Pt (100) towards methanol depends on surface structure and the nature and
amount of coadsorbed reaction modifiers. We studied the adsorption and reaction of CH3OH …

Surface-mediated hyperpolarization of liquid water from parahydrogen

EW Zhao, R Maligal-Ganesh, Y Du, TY Zhao, J Collins… - Chem, 2018 - cell.com
This article reports the discovery of surface-mediated parahydrogen-induced alignment of
the proton magnetic moments in liquid water as well as methanol and ethanol. In this …

Surface Structure Sensitivity of the Water−Gas Shift Reaction on Cu(hkl) Surfaces:  A Theoretical Study

Wang, L Jiang, Cai, Pan, Zhao, W Huang… - The Journal of …, 2003 - ACS Publications
The surface structure sensitivity of the water− gas shift (WGS) reaction (CO+ H2O→ CO2+
H2) over the Cu (111), Cu (100), and Cu (110) surfaces has been studied by first-principles …

Coadsorption of water and hydrogen on Pt (100): formation of adsorbed hydronium ions

N Kizhakevariam, EM Stuve - Surface science, 1992 - Elsevier
Coadsorption of water and hydrogen on Pt (100) was studied under conditions of ultrahigh
vacuum with thermal desorption spectroscopy and high resolution electron energy loss …

Formation of hydronium and water–hydronium complexes during coadsorption of hydrogen and water on (2× 1) Pt (110)

N Chen, P Blowers, RI Masel - Surface science, 1999 - Elsevier
In the previous literature, people have found that a new species forms when hydrogen and
water coadsorb on various faces of platinum. The new species was identified as “hydronium” …

Relating the in-situ, ex-situ, and non-situ environments in surface electrochemistry

EM Stuve, A Krasnopoler, DE Sauer - Surface science, 1995 - Elsevier
The relationship between ultrahigh vacuum surface science and electrochemistry is
examined by comparison of so-called non-situ and ex-situ experiments performed in the …