Beyond click chemistry–supramolecular interactions of 1, 2, 3-triazoles

B Schulze, US Schubert - Chemical Society Reviews, 2014 - pubs.rsc.org
The research on 1, 2, 3-triazoles has been lively and ever-growing since its stimulation by
the advent of click chemistry. The attractiveness of 1H-1, 2, 3-triazoles and their derivatives …

Chemical reactivity from an activation strain perspective

P Vermeeren, TA Hamlin, FM Bickelhaupt - Chemical Communications, 2021 - pubs.rsc.org
Chemical reactions are ubiquitous in the universe, they are at the core of life, and they are
essential for industrial processes. The drive for a deep understanding of how something …

The activation strain model and molecular orbital theory

LP Wolters, FM Bickelhaupt - Wiley Interdisciplinary Reviews …, 2015 - Wiley Online Library
The activation strain model is a powerful tool for understanding reactivity, or inertness, of
molecular species. This is done by relating the relative energy of a molecular complex along …

Cyclometalated (N, C) Au (III) Complexes: The Impact of Trans Effects on Their Synthesis, Structure, and Reactivity

MSM Holmsen, A Nova, M Tilset - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus The early years of gold catalysis were dominated by Au (I) complexes and
inorganic Au (III) salts. Thanks to the development of chelating ligands, more sophisticated …

Platinum‐Catalyzed Regio‐and Enantioselective Diboration of Unactivated Alkenes with (pin) B− B (dan)

H Fang, N Manoj, MV Popescu, A Noble… - Angewandte …, 2025 - Wiley Online Library
Asymmetric diboration of terminal alkenes is well established, and subsequent selective
functionalization of the less hindered primary boronic ester is commonly achieved …

Synthesis of platinum-containing conjugated polymers bearing chiral phosphine ligands. study of geometries and intermolecular interactions leading to aggregation

S Makino, T Horiuchi, T Ishida, N Sano, T Yajima… - …, 2022 - ACS Publications
Platinum (Pt)-containing conjugated polymers were synthesized by the dehydrochlorination
coupling polymerization of cis-and trans-dichlorobis (N-(p-(diphenylphosphino) benzoyl)-l …

Heterolytic splitting of molecular hydrogen by frustrated and classical Lewis pairs: a unified reactivity concept

G Skara, F De Vleeschouwer, P Geerlings… - Scientific Reports, 2017 - nature.com
Using a set of state-of-the-art quantum chemical techniques we scrutinized the
characteristically different reactivity of frustrated and classical Lewis pairs towards molecular …

New insights into Fe–H and Fe–H bonding of a [NiFe] hydrogenase mimic: a local vibrational mode study

MZ Makoś, M Freindorf, D Sethio, E Kraka - Theoretical Chemistry …, 2019 - Springer
In this work, we investigated the strength of the H^-H-and H _ 2 H 2 interaction with the Fe
atom of a NiFe hydrogenase mimic, and how this interaction can be modulated by changing …

Direct quantitative identification of the “surface trans-effect”

PS Deimel, RM Bababrik, B Wang, PJ Blowey… - Chemical …, 2016 - pubs.rsc.org
The strong parallels between coordination chemistry and adsorption on metal surfaces, with
molecules and ligands forming local bonds to individual atoms within a metal surface, have …

Controlled Access to Four- and Six-Membered Palladacycles via Modifying Donor Abilities of β-Ketiminato Ligands (“NacAcs”)

DCH Do, HV Huynh - Inorganic Chemistry, 2022 - ACS Publications
The synthesis of Pd complexes of the type [PdBr (i Pr2-bimy)(NacAc)](NacAc= β-ketiminate, i
Pr2-bimy= 1, 3-diisopropylbenzimidazolin-2-ylidene) was attempted, in a continuing effort to …