Supramolecular synthons in crystal engineering—a new organic synthesis

GR Desiraju - Angewandte Chemie International Edition in …, 1995 - Wiley Online Library
A crystal of an organic compound is the ultimate supermolecule, and its assembly, governed
by chemical and geometrical factors, from individual molecules is the perfect example of …

The C− H··· O hydrogen bond: structural implications and supramolecular design

GR Desiraju - Accounts of Chemical Research, 1996 - ACS Publications
The CH ‚‚‚O hydrogen bond is so well-established in structural chemistry that it seems
difficult now to believe that when Sutor proposed the existence of this type of hydrogen bond …

Fundamental properties of the CH⊙⊙⊙ O interaction: is it a true hydrogen bond?

Y Gu, T Kar, S Scheiner - Journal of the American Chemical …, 1999 - ACS Publications
Ab initio calculations are used to analyze the CH⊙⊙⊙ O interaction between F n H3-n CH
as proton donor and H2O, CH3OH, and H2CO as acceptor. The interaction is quite weak …

C‒H‒O hydrogen bonding in crystals

T Steiner - Crystallography Reviews, 1996 - Taylor & Francis
An overview is given on CHO hydrogen bonding in the solid state. Following a short survey
of the early literature, the general properties of CHO bonding are discussed. The structural …

Combining metals with halogen bonds

L Brammer, GM Espallargas, S Libri - CrystEngComm, 2008 - pubs.rsc.org
Halogen bonds in the solid state have been investigated for many years, with a major
resurgence in activity occurring in the past decade. The emphasis of most studies has been …

New trends in crystal engineering

D Braga, L Brammer, NR Champness - CrystEngComm, 2005 - pubs.rsc.org
The articles and highlights presented at the second CrystEngComm meeting, held in
Nottingham in September 2004 are reviewed. The discussion has highlighted the current …

Unrolling the hydrogen bond properties of C–H··· O interactions

T Steiner - Chemical Communications, 1997 - pubs.rsc.org
It has long been known that C–H groups may form weak hydrogen bonds. The
characteristics of these interactions, however, have been explored systematically only …

The C–H··· Cl hydrogen bond: does it exist?

CB Aakeröy, TA Evans, KR Seddon… - New Journal of Chemistry, 1999 - pubs.rsc.org
The extensive occurrence of C–H··· Cl hydrogen bonds has been established through a
systematic statistical analysis of the Cambridge Crystallographic Database; chloride anions …

Metal-bound chlorine often accepts hydrogen bonds

G Aullón, D Bellamy, AG Orpen, L Brammer… - Chemical …, 1998 - pubs.rsc.org
Analysis of 6624 crystallographically characterised hydrogen bonds containing M–Cl, C–Cl
or Cl–and either HO or HN groups show that M–Cl moieties are good, anisotropic hydrogen …

Crystal engineering: from weak hydrogen bonds to co-ordination bonds

K Biradha - CrystEngComm, 2003 - pubs.rsc.org
This article highlights the importance of crystal engineering in designing functional
materials. Various rational design strategies will be discussed for controlling the molecular …