The hallmark of nucleophilic phosphine catalysis is the initial nucleophilic addition of a
phosphine to an electrophilic starting material, producing a reactive zwitterionic …

Asymmetric phosphine catalysis showcasing remarkable progress over the past two
decades has emerged as a key synthetic platform for the creation of molecular frameworks …

The goal of this review is to collect the recent developments in asymmetric organocatalytic
(aza)-Morita− Baylis− Hillman reactions reported since the beginning of 2013. It also …

We developed novel shackled P-chiral ligands based on 1-phosphanorbornenes and
oxazolines. They were subsequently evaluated in palladium-catalyzed (4+ 2) annulations …

A type of Morita–Baylis–Hillman (MBH) carbonates has been developed from ninhydrin.
These MBH carbonates have been successfully employed as 3C-synthons in the …

A phosphine-catalyzed cascade annulation of Morita–Baylis–Hillman (MBH) carbonates and
diazenes was achieved, giving tetrahydropyrazole-fused heterocycles bearing two five …

Nitrogen‐containing heterocyclic compounds have consistently been a noticeable center of
attention due to their significant utilization in the domain of synthetic organic chemistry …

A series of γ-substituted Morita–Baylis–Hillman (MBH) carbonates were synthesized and
subjected to phosphine-catalyzed annulations with electrophilic exocyclic alkenes, giving …

Abstract Phosphine‐catalyzed (4+ 2) annulation of the acidic hydrogen‐tethered allylic
carbonates with electron‐deficient alkenes was achieved. Various electron‐deficient …

We have prepared a previously unreported family of P-stereogenic [2.2. 1] bicyclic chiral
phosphines through straightforward syntheses starting from the natural product carvone …