Conspectus Oxidation reactions play a central role in organic synthesis, and it is highly
desirable that these reactions are mild and occur under catalytic conditions. In Nature …

Carbon monoxide, which is an abundant and inexpensive carbonyl source, has been widely
applied to synthesize carbonyl-containing compounds, for example ketones, esters, and …

Carbonyl derivatives widely exist in pharmaceuticals, agricultural chemicals, materials, and
natural products. Developing novel, efficient, and green carbonylation methods represent …

In this account, we review our efforts in the field of carbonylation reactions promoted by
palladium iodide-based catalysts, which have proven to be particularly efficient in diverse …

An efficient double allene protocol for the formation of benzazocines has been developed.
The reaction constitutes a highly regioselective palladium‐catalyzed formal [6+ 2] annulation …

Herein, we report an electrochemical oxidative palladium‐catalyzed carbonylation‐
carbocyclization of enallenols to afford γ‐lactones and spirolactones, which proceeds with …

A palladium-catalyzed oxidative tandem process of enallenols was accomplished within a
homogeneous/heterogeneous catalysis manifold, setting the stage for the highly …

In this work, we have described the carbonylative synthesis of amides from aryl iodides and
tertiary amines as an aminal source via oxidant‐free C (sp3)− N bond cleavage using in situ …

A general palladium‐catalyzed synthesis of linear esters directly from sec‐and tert‐alcohols
is described. Compared to the classic Koch–Haaf reaction, which leads to branched …

Herein, we describe an efficient nanocopper-catalyzed Alder-ene reaction of allenynamides.
The copper nanoparticles were immobilized on amino-functionalized microcrystalline …