Di-and tetra-nuclear oxorhenium (V) complexes of benzoylthiourea derivative ligands: Synthesis, structural characterization, and catalytic applications

E Keskin, U Solmaz, I Gumus, H Arslan - Polyhedron, 2022 - Elsevier
Two benzoylthiourea derivative compounds (H 2 L 1 and H 2 L 2) derived from isophthaloyl
diisothiocyanate was prepared and applied as a ligand for the preparation of di-and tetra …

Rhenium (V) oxocomplexes [ReOX (N–O) 2] and [ReOL (N–O) 2]+—Synthesis, structure, spectroscopy and catalytic properties

B Machura, M Wolff, I Gryca - Coordination Chemistry Reviews, 2014 - Elsevier
The present review aims to give a comprehensive survey about the chemistry of rhenium (V)
oxo complexes of general formula [ReOX (N–O) 2] and [ReOL (N–O) 2]+, where X= Cl, Br; …

Configuration control in the synthesis of homo-and heteroleptic bis (oxazolinylphenolato/thiazolinylphenolato) chelate ligand complexes of oxorhenium (V): Isomer …

J Liu, D Wu, X Su, M Han, SY Kimura, DL Gray… - Inorganic …, 2016 - ACS Publications
This study develops synthetic strategies for N, N-trans and N, N-cis Re (O)(LO–N) 2Cl
complexes and investigates the effects of the coordination spheres and ligand structures on …

Oxorhenium (V) complexes with phenolate–oxazoline ligands: influence of the isomeric form on the O-atom-transfer reactivity

JA Schachner, B Terfassa, LM Peschel… - Inorganic …, 2014 - ACS Publications
The bidentate phenolate–oxazoline ligands 2-(2′-hydroxyphenyl)-2-oxazoline (1a, Hoz)
and 2-(4′, 4′-dimethyl-3′, 4′-dihydrooxazol-2′-yl) phenol (1b, Hdmoz) were used to …

Ca (II)-catalyzed diastereoselective formal [4+ 2] annulation of a 3-component solvent-free povarov reaction

PMK Mohinuddin, R Dada, AI Almansour… - Tetrahedron …, 2019 - Elsevier
Diastereoselective, three-component annulation reaction involving glyoxals, anilines and
dienophiles is developed under calcium catalysis. When indene is the dienophile, the …

Acid‐Activated Carbon Materials: Cheaper Alternative Catalysts for the Synthesis of Substituted Quinolines

J López‐Sanz, E Pérez‐Mayoral, E Soriano… - …, 2013 - Wiley Online Library
We describe the first examples of Friedländer reactions efficiently catalyzed by carbon
materials. We report herein a series of acidic activated carbon materials, which can be …

From Surprising Solvothermal Reaction to Uncommon Zinc (II)-Catalyzed Aromatic C–H Activation Reaction for Direct Nitroquinoline Synthesis

Y Wang, F Yu, X Han, M Li, Y Tong, J Ding… - Inorganic …, 2017 - ACS Publications
In this work, we first found a surprising solvothermal reaction for direct dinitration of quinoline
derivative. To explore the application in direct nitroquinoline synthesis, this reaction was …

Oxorhenium (V) complexes with phenolate–pyrazole ligands for olefin epoxidation using hydrogen peroxide

N Zwettler, JA Schachner, F Belaj… - Inorganic …, 2014 - ACS Publications
Oxorhenium (V) complexes of the general formula [ReOCl2 (PPh3)(L)](2a–c) and [ReOCl (L)
2](3a–c) with L being monoanionic, bidentate phenolate–pyrazole ligands 1a–c that bear …

Dinuclear and mononuclear oxorhenium (V) complexes chelated with the S, O bidentate thiourea ligand: Synthesis, crystal structure and catalytic activity

S Bozkurt, I Gumus, H Arslan - Journal of Organometallic Chemistry, 2019 - Elsevier
Abstract N-(Diethylcarbamothioyl)-4-methylbenzamide ligand (HL) was prepared by
subsequent reactions of p-toluoyl chloride with potassium thiocyanate and di-n-ethylamine …

Oxidorhenium (V) complexes with tetradentate iminophenolate ligands: influence of ligand flexibility on the coordination motif and oxygen-atom-transfer activity

N Zwettler, JA Schachner, F Belaj… - Inorganic …, 2016 - ACS Publications
The synthesis of oxidorhenium (V) complexes 1–3 coordinated by tetradentate
iminophenolate ligands H 2 L1–H 2 L3 bearing backbones of different rigidity (alkyl …