Inherently chiral concave molecules—from synthesis to applications

A Szumna - Chemical Society Reviews, 2010 - pubs.rsc.org
This tutorial review covers the recent development in the synthesis and application of
molecules and finite assemblies that are chiral owing to their curvature. A modified definition …

Synthesis of novel pillar-shaped cavitands “Pillar [5] arenes” and their application for supramolecular materials

T Ogoshi - Journal of Inclusion Phenomena and Macrocyclic …, 2012 - Springer
In 2008, we reported a new class of macrocyclic hosts and named “Pillar [5] arenes”. They
combine the advantages and aspects of traditional hosts and have a composition similar to …

Self-assembly of amphiphilic calixarenes and resorcinarenes in water

K Helttunen, P Shahgaldian - New Journal of Chemistry, 2010 - pubs.rsc.org
The calixarenes and resorcinarenes are macrocyclic phenolic molecules that can be
modified “à façon” and a wide range of chemical modification strategies have been …

Asymmetric Synthesis of Enantioenriched Zigzag-Type Molecular Belts by Kinetic Resolution and Subsequent Transformations

YQ Mao, Y Zhang, S Tong, J Zhu, MX Wang - Organic Letters, 2023 - ACS Publications
Asymmetric synthesis of enantioenriched zigzag-type molecular belts featuring copper/H8-
binaphthol-catalyzed kinetic resolution of a resorcinarene derivative and subsequent …

A brief review of C n -symmetric calixarenes and resorcinarenes

MJ McIldowie, M Mocerino, MI Ogden - Supramolecular Chemistry, 2010 - Taylor & Francis
Calixarene and resorcinarene macrocycles are renowned for their ability to form inclusion
complexes or act as molecular scaffolds. The addition of chirality to these non-planar …

Catechol [4] arene: the missing chiral member of the calix [4] arene family

SJ Nemat, H Jedrzejewska, A Prescimone… - Organic …, 2020 - ACS Publications
A missing, inherently chiral member of the calix [4] arene family denoted “catechol [4] arene”
was synthesized. Its properties were studied and compared to the ones of its close relatives …

Hybrid [n]Arenes through Thermodynamically Driven Macrocyclization Reactions

T Boinski, A Cieszkowski, B Rosa… - The Journal of Organic …, 2015 - ACS Publications
Hybrid [n] arenes, the class of medium-sized macrocyclic compounds consisting of different
alkoxybenzene units, were obtained by a simple, one-pot, direct condensation of two …

Coumarin [4] arene: a fluorescent macrocycle

P Kumar, P Venkatakrishnan - Organic letters, 2018 - ACS Publications
The pyranone functionalization of the upper rim of resorcinarene to provide the coumarin
macrocycle called “coumarin [4] arene”, possessing visible fluorescence and …

Synthesis and conformational characteristics of nonsymmetric pillar [5] arene

T Ogoshi, K Kitajima, T Yamagishi, Y Nakamoto - Organic Letters, 2010 - ACS Publications
A new nonsymmetric pillar [5] arene of ethoxymethoxypillar [5] arene (EMpillar [5] arene) has
been synthesized. By 2D ROESY analysis of EMpillar [5] arene, the ethoxy and methoxy …

Synthesis and characterization of two sulfonated resorcinarenes: A new example of a linear array of sodium centers and macrocycles

E Sanabria, MÁ Esteso, A Pérez-Redondo, E Vargas… - Molecules, 2015 - mdpi.com
Two sulfonated resorcinarenes were synthesized by reacting C-tetra (butyl) resorcinarene or
C-tetra (2-(methylthio) ethyl) resorcinarene with formaldehyde in the presence of sodium …