[(CoCp2) ⊂ Fe(μ‐CNSnMe3NC)3]: A Purely Organometallic Channel Inclusion Compound

P Schwarz, E Siebel, RD Fischer… - … Edition in English, 1995 - Wiley Online Library
Inclusion compounds with metallocene guest components are of interest not only in
fundamental research, but also increasingly in materials science.['.'] So far, metal …

Polymorphism of potassium ferrocyanide trihydrate as studied by solid-state multinuclear NMR spectroscopy and X-ray diffraction

MJ Willans, RE Wasylishen, R McDonald - Inorganic chemistry, 2009 - ACS Publications
The polymorphism of bulk powder samples of potassium ferrocyanide trihydrate (K4Fe (CN)
6· 3H2O, KFCT) has been studied using 1H, 13C, and 15N NMR spectroscopy in …

Organolead (IV) polymers [(Me3Pb) 4M (CN) 6· nH2O] with M= Fe and Ru (0≤ n≤ 2): solid-state NMR and vibrational spectroscopy; crystal structure of the dihydrates

AK Brimah, P Schwarz, RD Fischer, NA Davies… - Journal of …, 1998 - Elsevier
From aqueous solutions of Me3PbCl and K4 [M (CN) 6](4: 1; M= Fe or Ru), primarily the
diaqua compounds [(Me3Pb) 4M (CN) 6· 2H2O], 4a and 4b, precipitate. These turn out to be …

DFT calculations of 119 Sn chemical shifts for organometallic cyanides

P Avalle, RK Harris, RD Fischer - Physical Chemistry Chemical Physics, 2002 - pubs.rsc.org
Density functional theory (B3LYP) calculations have been carried out for 119Sn isotropic
chemical shifts for a grouping C–N–Sn (CH3) 3–N–C characteristic of a series of solid …

Magic-angle spinning NMR spectra and re-examined crystal structure of trimethyltin cyanide

P Avalle, RK Harris, H Hanika-Heidl, RD Fischer - Solid state sciences, 2004 - Elsevier
The structure of crystalline trimethyltin cyanide has been studied by magic-angle spinning
NMR, by DFT computations and by single-crystal X-ray diffraction. An earlier diffraction study …

Unprecedented N–E Bond Cleavage (E= Sn, Pb) by R4N+ Ions (R= nBu, nPr): Formation, Architecture, and Multinuclear Magnetic Resonance Spectroscopy of Novel …

P Schwarz, E Siebel, RD Fischer… - … A European Journal, 1998 - Wiley Online Library
Hydrogen bonds of the two types O− H⋅⋅⋅ N and C− H⋅⋅⋅ N (shortest C⋅⋅⋅ N contact:
317.3 pm) seem to dictate the supramolecular architecture of novel host–guest systems …

Simple quaternary ammonium ions R4N+ (R= nPr, nBu, nPen) as versatile structure directors for the synthesis of zeolite-like, heterobimetallic cyanide frameworks

EM Poll, S Samba, RD Fischer, F Olbrich… - Journal of Solid State …, 2000 - Elsevier
The preparation of three new examples of water insoluble host/guest assemblies of the
general composition:[(R4N)(Me3Sn) 2M (CN) 6· zH2O](R= n-propyl or n-pentyl, M= Fe or …

Self-assembly of [Cu (CN) 4] 3− ions with cationic {Me3Sn}+ or {Me2Sn (CH2) 3SnMe2} 2+ fragments in the presence of a nBu4N+ template

EM Poll, JU Schütze, RD Fischer, NA Davies… - Journal of …, 2001 - Elsevier
As described earlier, solutions of nBu4NCl and K3 [Cu (CN) 4] react with Et3SnCl to zeolite-
like [(Bu4N)(Et3Sn) 2Cu (CN) 4](1), but with Me3SnCl exclusively to [(Bu4N)(Me3Sn) Cu2 …

Template‐Driven Syntheses of Polymeric Metal Cyanides: A Chiral Nanoporous Host for the nBu4N+ Ion

P Schwarz, S Eller, E Siebel… - … Edition in English, 1996 - Wiley Online Library
A comfortable fit is provided for the large tetrabutylammonium ion within the wide channels
of the new host–guest compound [(nBu4N) 0.5 (Me3Sn) 3.5 Fe (CN) 6]. The lipophilic walls …

In Situ Monitoring of Solid‐State Polymerization Reactions in Sodium Chloroacetate and Sodium Bromoacetate by 23Na and 13C Solid‐State NMR Spectroscopy

AE Aliev, L Elizabé, BM Kariuki… - … A European Journal, 2000 - Wiley Online Library
The thermally induced solid‐state polymerization reactions in sodium chloroacetate and
sodium bromoacetate, leading to poly (hydroxyacetic acid)(polyglycolide) and NaCl and …