Metal borohydrides and derivatives–synthesis, structure and properties
M Paskevicius, LH Jepsen, P Schouwink… - Chemical Society …, 2017 - pubs.rsc.org
A wide variety of metal borohydrides, MBH4, have been discovered and characterized
during the past decade, revealing an extremely rich chemistry including fascinating …
during the past decade, revealing an extremely rich chemistry including fascinating …
[HTML][HTML] Complex hydrides for hydrogen storage–new perspectives
Since the 1970s, hydrogen has been considered as a possible energy carrier for the storage
of renewable energy. The main focus has been on addressing the ultimate challenge …
of renewable energy. The main focus has been on addressing the ultimate challenge …
Single─Not Double─3D-Aromaticity in an Oxidized Closo Icosahedral Dodecaiodo-Dodecaborate Cluster
3D-aromatic molecules with (distorted) tetrahedral, octahedral, or spherical structures are
much less common than typical 2D-aromatic species or even 2D-aromatic-in-3D systems …
much less common than typical 2D-aromatic species or even 2D-aromatic-in-3D systems …
Hydrogen storage materials for mobile and stationary applications: current state of the art
One of the limitations to the widespread use of hydrogen as an energy carrier is its storage
in a safe and compact form. Herein, recent developments in effective high‐capacity …
in a safe and compact form. Herein, recent developments in effective high‐capacity …
Converting H+ from coordinated water into H− enables super facile synthesis of LiBH 4
LiBH4 has excellent application potential as an off-or on-board hydrogen carrier for its
unparalleled hydrogen capacity (18.5 wt%). However, the difficulty in recycling “one-pass” …
unparalleled hydrogen capacity (18.5 wt%). However, the difficulty in recycling “one-pass” …
Inorganic solid electrolytes for all‐solid‐state sodium batteries: fundamentals and strategies for battery optimization
Recent realization of high sodium‐ion conductivities (> 10− 2 S cm− 1) in inorganic solid
electrolytes (ISEs) at room temperature will certainly trigger a boom in all‐solid‐state sodium …
electrolytes (ISEs) at room temperature will certainly trigger a boom in all‐solid‐state sodium …
π Aromaticity and three‐dimensional aromaticity: two sides of the same coin?
A bridge between classical organic polycyclic aromatic hydrocarbons (PAH) and closo
borohydride clusters is established by showing that they share a common origin regulated …
borohydride clusters is established by showing that they share a common origin regulated …
Three-Dimensional Fully π-Conjugated Macrocycles: When 3D-Aromatic and When 2D-Aromatic-in-3D?
Several fully π-conjugated macrocycles with puckered or cage-type structures were recently
found to exhibit aromatic character according to both experiments and computations. We …
found to exhibit aromatic character according to both experiments and computations. We …
Sodium superionic conduction in Na 2 B 12 H 12
TJ Udovic, M Matsuo, A Unemoto, N Verdal… - Chemical …, 2014 - pubs.rsc.org
Impedance measurements indicate that Na2B12H12 exhibits dramatic Na+ conductivity (on
the order of 0.1 S cm− 1) above its order-disorder phase-transition at≈ 529 K, rivaling that of …
the order of 0.1 S cm− 1) above its order-disorder phase-transition at≈ 529 K, rivaling that of …
Status and prospects of hydroborate electrolytes for all-solid-state batteries
Hydroborates represent a promising, yet underexplored, class of electrolytes for all-solid-
state batteries. This article reviews the rapid recent developments that enabled the …
state batteries. This article reviews the rapid recent developments that enabled the …