Atomically precise alloy nanoclusters: syntheses, structures, and properties

X Kang, Y Li, M Zhu, R Jin - Chemical Society Reviews, 2020 - pubs.rsc.org
Metal nanoclusters fill the gap between discrete atoms and plasmonic nanoparticles,
providing unique opportunities for investigating the quantum effects and precise structure …

Atomically precise noble metal nanoclusters as efficient catalysts: a bridge between structure and properties

Y Du, H Sheng, D Astruc, M Zhu - Chemical reviews, 2019 - ACS Publications
Improving the knowledge of the relationship between structure and properties is
fundamental in catalysis. Recently, researchers have developed a variety of well-controlled …

Atomically precise colloidal metal nanoclusters and nanoparticles: fundamentals and opportunities

R Jin, C Zeng, M Zhou, Y Chen - Chemical reviews, 2016 - ACS Publications
Colloidal nanoparticles are being intensely pursued in current nanoscience research.
Nanochemists are often frustrated by the well-known fact that no two nanoparticles are the …

Atomic-level doping of metal clusters

A Ghosh, OF Mohammed, OM Bakr - Accounts of Chemical …, 2018 - ACS Publications
Conspectus Atomically precise noble metal (mainly silver and gold) nanoclusters are an
emerging category of promising functional materials for future applications in energy …

Molecular reactivity of thiolate-protected noble metal nanoclusters: synthesis, self-assembly, and applications

Q Yao, Z Wu, Z Liu, Y Lin, X Yuan, J Xie - Chemical Science, 2021 - pubs.rsc.org
Thiolate-protected noble metal (eg, Au and Ag) nanoclusters (NCs) are ultra-small particles
with a core size of less than 3 nm. Due to the strong quantum confinement effects and …

Customizing the structure, composition, and properties of alloy nanoclusters by metal exchange

S Wang, Q Li, X Kang, M Zhu - Accounts of chemical research, 2018 - ACS Publications
Conspectus The properties of metal materials can be greatly enriched by including various
elements to generate alloys. The galvanic replacement represents a classical method for the …

Thiolate‐protected metal nanoclusters: recent development in synthesis, understanding of reaction, and application in energy and environmental field

T Kawawaki, A Ebina, Y Hosokawa, S Ozaki, D Suzuki… - Small, 2021 - Wiley Online Library
Metal nanoclusters (NCs), which are composed of about 250 or fewer metal atoms, possess
great potential as novel functional materials. Fundamental research on metal NCs gradually …

Precise synthesis, functionalization and application of thiolate-protected gold clusters

W Kurashige, Y Niihori, S Sharma, Y Negishi - Coordination Chemistry …, 2016 - Elsevier
Thiolate-protected gold clusters (Au n (SR) m) have received significant attention as new
functional nanomaterials because they exhibit size-specific physical and chemical …

Thiolated gold nanoclusters for light energy conversion

MA Abbas, PV Kamat, JH Bang - ACS Energy Letters, 2018 - ACS Publications
Few-atom gold nanoclusters (NCs) exhibit molecule-like properties due to a discrete
electronic structure driven by the quantum confinement effect. Unlike plasmonic Au particles …

Atomically precise thiolate‐protected gold nanoclusters: Current status of designability of the structure and physicochemical properties

S Hossain, D Hirayama, A Ikeda, M Ishimi… - …, 2023 - Wiley Online Library
Thiolate (SR)‐protected gold nanoclusters (Aun (SR) m NCs) are a rare type of material
capable of simultaneously exhibiting multiple physicochemical properties well‐suited to …