Dimethyl sulfoxide (DMSO), as extremely important aprotic polar solvent and reaction
medium, has attracted widespread attention from chemists in recent years due to its wide …

This paper describes the design of poly (benzyl ether)-based amphiphiles that are capable
of selective and molecular demicellization via head-to-tail depolymerization, triggered by a …

A new tandem annulation of p-quinone methides (p-QMs) with ynamides is described. This
cascade reaction features a unique combination of (2+ 2) annulation, retro-4π …

The cationic Ru–H complex [(C6H6)(PCy3)(CO) RuH]+ BF4–(1) was found to be an effective
catalyst for the dehydrative C–H coupling reaction of phenols and aldehydes to form 2 …

The second-order rate constants (k) for the nucleophilic aromatic substitution reactions of 2‑
methoxy-3, 5-dinitropyridine 1 with secondary cyclic amines 2a-c in acetonitrile solution at …

Chiral isochalcogenoureas (ie isothioureas and isoselenoureas) catalyse the asymmetric
(4+ 2)-cycloaddition of various allenoates with ortho-quinone methides. This approach …

An efficient, secondary amine-catalyzed cascade annulation of 2-O/N-
propargylarylaldehydes with 2, 6-dialkylphenols was established to access biologically …

Diazophosphonates function as indispensable synthetic intermediates within the domain of
organic chemistry, serving as precursors for a diverse range of molecules, with potential …

Electrophilicity (E) is one of the most important parameters to understand the reactivity of an
organic molecule. Although the theoretical electrophilicity index (ω) has been associated …

Cyclopropanes that carry an electron-accepting group react as electrophiles in polar, ring-
opening reactions. Analogous reactions at cyclopropanes with additional C2 substituents …