Photoinduced chemical transformations have received in recent years a tremendous amount of attention, providing a plethora of opportunities to synthetic organic chemists. However …
JD Bell, JA Murphy - Chemical Society Reviews, 2021 - pubs.rsc.org
Photoredox chemistry with organic or transition metal agents has been reviewed in earlier years, but such is the pace of progress that we will overlap very little with earlier …
We present here a review of the photochemical and electrochemical applications of multi- site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …
N Holmberg-Douglas, DA Nicewicz - Chemical reviews, 2021 - ACS Publications
The fields of C–H functionalization and photoredox catalysis have garnered enormous interest and utility in the past several decades. Many different scientific disciplines have …
Second-and third-row transition metal complexes are widely employed in photocatalysis, whereas earth-abundant first-row transition metals have found only limited use because of …
Hydrogen-atom transfer (HAT) provides straightforward methods to generate open-shell radical intermediates from RH (R= C, Si, etc.) bonds and offers unique opportunities for …
T Tian, Z Li, CJ Li - Green Chemistry, 2021 - pubs.rsc.org
We are entering an era that emphasizes greenness and sustainability. Based on such a philosophy, it is critical to uncover novel and original sustainable reaction modes for future …
We report herein a modular class of organic catalysts that, acting as donors, can readily form photoactive electron donor–acceptor (EDA) complexes with a variety of radical precursors …
Reactions that involve the addition of carbon‐centered radicals to basic heteroarenes, followed by formal hydrogen atom loss, have become widely known as Minisci‐type …