Discrete transition-metal clusters with metal–metal or metal–oxygen–metal bonds represent
a new category of functional materials with numerous unusual properties. For instance, the …

Enamines exhibit exceptionally high reactivity in their 1, 3‐dipolar cycloaddition reactions
with azides in comparison with other dipolarophiles. This review includes the reactions of …

Tetrasubstituted 1H‐imidazoles are a large family of heteroarene derivatives that are known
to include natural products isolated from marine sponges and synthetic compounds …

An anti-carbonickelative cyclization via reversible alkenylnickel E/Z isomerization of 2-azido
phenyl propargyl alcohols with aryl boronic acids is achieved using Ni (acac) 2 as the …

A base promoted, protection-free, and regioselective synthesis of highly functionalized
quinolines via [4+ 2] cycloaddition of azadienes (generated in situ from o-aminobenzyl …

The purpose of this review is to highlight ten years of success in the synthesis of six-
membered N-heterocycles using alkynes and nitrogen sources as substrates. It is our hope …

A general method for isoxazoles from readily available ynones using trimethylsilyl azide as
an amino surrogate, likely via an unprecedented hydroazidation of the alkyne and …

An unprecedented conversion of terminal alkynes into N-sulfonimidamides (amidines) is
reported by a silver-catalyzed, one-pot, four-component reaction with TMSN3, sodium …

An unprecedented Lewis acid catalyzed [4+ 3] cycloaddition reaction is described that
provides a straightforward route to polycyclic products containing an imine-based indole …

Addition of arylboronic acids to directing group tethered acetylenes in a regio and
stereoselective manner using an inexpensive catalytic system is achieved for the first time to …