Background: The complex photochemistry of aryl azides has fascinated scientists for several
decades. Spectroscopists have investigated the intermediates formed by different analytical …

For several decades, aromatic azides have been applied in diverse areas of research like
synthesis of organic compounds, novel materials and photoaffinity labeling of biomolecules …

Controlling the end‐groups of biocompatible polymers is crucial for enabling polymer‐based
therapeutics and nanomedicine. Typically, end‐group diversification is a challenging and …

The creation of new bonds via C–F bond cleavage of polyfluoroarenes has proven to be an
important and powerful tool in synthetic chemistry. Using such a strategy, a myriad of …

Two fast and mild methodologies to prepare nitrophenyl and fluorophenyl azides are
presented. These aryl azides are extensively used as crosslinking, photoaffinity labeling …

A simple and efficient route for the construction of 2, 3, 5, 6-tetrafluorobenzonitrile-
substituted dithiocarbamic acid esters via selective C–F bond cleavage of …

Abstract A series of 1-polyfluoroaryl-1, 2, 3-triazoles were synthesized in moderate to good
yields by an efficient copper-catalyzed one-pot three-component reaction of …

Reactivity and regioselectivity of SNAr‐type fluorine substitution with azide in
polyfluoronitrobenzenes was studied both theoretically and experimentally. The obtained …

A strategy for direct alkynylation of electron-deficient octafluorotoluene via selective C–F
bond cleavage is exhibited. The synthesized products are super intermediates for further …

Background: According to the World Health Organization (WHO), the fight against Acquired
Immunodeficiency Syndrome (AIDS) is still one of the most significant challenges facing …