A journey into the electrochemistry of vanadium compounds
Vanadium is an element with a fascinating history, a widespread diffusion in bacteria and
eukaryan organisms, and rich coordination chemistry. The properties of vanadium …
eukaryan organisms, and rich coordination chemistry. The properties of vanadium …
Probing the synthetic protocols and coordination chemistry of oxido-, dioxido-, oxidoperoxido-vanadium and related complexes of higher nuclearity
MR Maurya - Coordination Chemistry Reviews, 2019 - Elsevier
Syntheses of vanadium complexes of higher oxidation states (+ IV and+ V) are mostly
influenced by metal precursors, the nature of the ligands, reaction conditions, solvents …
influenced by metal precursors, the nature of the ligands, reaction conditions, solvents …
Is vanadate reduced by thiols under biological conditions? Changing the redox potential of V (V)/V (IV) by complexation in aqueous solution
DC Crans, B Zhang, E Gaidamauskas… - Inorganic …, 2010 - ACS Publications
Although dogma states that vanadate is readily reduced by glutathione, cysteine, and other
thiols, there are several examples documenting that vanadium (V)− sulfur complexes can …
thiols, there are several examples documenting that vanadium (V)− sulfur complexes can …
Diastereomeric dinickel (II) complexes with non-innocent bis (octaazamacrocyclic) ligands: isomerization, spectroelectrochemistry, DFT calculations and use in …
A Dobrov, D Darvasiová, M Zalibera, L Bučinský… - Dalton …, 2022 - pubs.rsc.org
Diastereomeric dinickel (II) complexes with bis-octaazamacrocyclic 15-membered ligands
[Ni (L1–3–L1–3) Ni](4–6) have been prepared by oxidative dehydrogenation of nickel (II) …
[Ni (L1–3–L1–3) Ni](4–6) have been prepared by oxidative dehydrogenation of nickel (II) …
Synthesis of vitamin E and aliphatic lipid vanadium (IV) and (V) complexes, and their cytotoxic properties
Novel vitamin E chelate derivatives and their V IV/V complexes have been synthesized and
characterized, and their anticancer properties have been evaluated. The new complexes …
characterized, and their anticancer properties have been evaluated. The new complexes …
Four electron selective O 2 reduction by a tetranuclear vanadium (IV/V)/hydroquinonate catalyst: application in the operation of Zn–air batteries
The reduction of dioxygen plays a crucial role in both natural and artificial systems exhibiting
peroxidase like activity, utilizing O2 as a cheap and green oxidant in several applications …
peroxidase like activity, utilizing O2 as a cheap and green oxidant in several applications …
Vanadium-induced nucleophilic ipso substitutions in a coordinated tetrachlorosemiquinone ring: Formation of the chloranilate anion as a bridging ligand
PB Chatterjee, K Bhattacharya, N Kundu… - Inorganic …, 2009 - ACS Publications
In basic media, the coordinated semiquinone radical in the spin-coupled [(bipy) ClVIVO
(TCSQ)] 1 (HTCSQ= tetrachlorosemiquinone) undergoes nucleophilic ipso substitution (OH …
(TCSQ)] 1 (HTCSQ= tetrachlorosemiquinone) undergoes nucleophilic ipso substitution (OH …
Vanadium (V) complexes with siderophore vitamin E-hydroxylamino-triazine ligands
M Loizou, I Hadjiadamou, C Drouza, AD Keramidas… - Inorganics, 2021 - mdpi.com
Novel vitamin E chelate siderophore derivatives and their VV and FeIII complexes have
been synthesised and the chemical and biological properties have been evaluated. In …
been synthesised and the chemical and biological properties have been evaluated. In …
Investigation of Phenols Activity in Early Stage Oxidation of Edible Oils by Electron Paramagnetic Resonance and 19F NMR Spectroscopies Using Novel Lipid …
C Drouza, A Dieronitou, I Hadjiadamou… - Journal of agricultural …, 2017 - ACS Publications
A novel dynamic method for the investigation of the phenols activity in early stage oxidation
of edible oils based on the formation of α-tocopheryl radicals initiated by oil-soluble …
of edible oils based on the formation of α-tocopheryl radicals initiated by oil-soluble …
o-Iminobenzosemiquinonate and o-Imino-p-methylbenzosemiquinonate Anion Radicals Coupled VO2+ Stabilization
The diamagnetic VO2+-iminobenzosemiquinonate anion radical (LRIS•−, R= H, Me)
complexes,(L−)(VO2+)(LRIS•−):(L1−)(VO2+)(LHIS•−)• 3/2MeOH (1• 3/2MeOH),(L2−)(VO2+) …
complexes,(L−)(VO2+)(LRIS•−):(L1−)(VO2+)(LHIS•−)• 3/2MeOH (1• 3/2MeOH),(L2−)(VO2+) …