Controlled polymerization methods are well-established synthetic protocols for the design and preparation of polymeric materials with a high degree of precision over molar mass and …
We present the bulk depolymerization of poly (methyl methacrylate)(PMMA) at significantly lower temperatures than previously reported methods through the incorporation of …
A photocatalytic ATRP depolymerization is introduced that significantly suppresses the reaction temperature from 170 to 100° C while enabling temporal regulation. In the presence …
Fast bulk depolymerization of poly (n-butyl methacrylate) and poly (methyl methacrylate), prepared by atom transfer radical polymerization (ATRP), is reported in the temperature …
LH Kugelmass, C Tagnon… - Journal of the American …, 2023 - ACS Publications
Plastic recycling strategies to combat rapidly increasing waste buildup are of utmost environmental importance. Chemical recycling to monomers has emerged as a powerful …
We establish a synthetically convenient method to degrade polyacrylate homopolymers. Carboxylic acids are installed along the polymer backbone by partial hydrolysis of the ester …
Although controlled radical polymerization is an excellent tool to make precision polymeric materials, reversal of the process to retrieve the starting monomer is far less explored …
Depolymerization of polymers synthesized by reversible deactivation radical polymerization (RDRP) has recently emerged as a promising chemical recycling method for a circular …
F Eisenreich - Angewandte Chemie International Edition, 2023 - Wiley Online Library
Shaping a sustainable future is closely tied to the development of advanced plastic recycling technologies. As global recycling rates remain low, the lion's share of post‐consumer …