Insights into Cation Migration and Intermixing in Advanced Cathode Materials for Lithium‐Ion Batteries

S Zhang, Z Yang, Y Lu, W Xie, Z Yan… - Advanced Energy …, 2024 - Wiley Online Library
Cathode materials are the core components of lithium‐ion batteries owing to the
determination of the practical voltage and effective energy of the battery system. However …

Empowering higher energy sodium‐ion battery cathode by oxygen chemistry

G Wan, W Dou, H Zhu, W Zhang, T Liu… - Interdisciplinary …, 2023 - Wiley Online Library
Abstract Sodium (Na) ion batteries (SIBs) promise low‐cost energy storage systems but are
still restricted by insufficient energy density. Introducing oxygen (O) redox into the design of …

High-entropy single-atom activated carbon catalysts for sustainable oxygen electrocatalysis

X Lei, Q Tang, Y Zheng, P Kidkhunthod, X Zhou… - Nature …, 2023 - nature.com
The electrocatalytic oxygen reduction and evolution of molecular oxygen, known as oxygen
electrocatalysis, is one of the most important reactions that are central to a range of energy …

Realizing high capacity and zero strain in layered oxide cathodes via lithium dual-site substitution for sodium-ion batteries

Z Wu, Y Ni, S Tan, E Hu, L He, J Liu… - Journal of the …, 2023 - ACS Publications
Sodium-ion batteries have garnered unprecedented attention as an electrochemical energy
storage technology, but it remains challenging to design high-energy-density cathode …

Defective oxygen inert phase stabilized high-voltage nickel-rich cathode for high-energy lithium-ion batteries

Z Dai, Z Li, R Chen, F Wu, L Li - Nature Communications, 2023 - nature.com
Pushing layered cathode to higher operating voltage can facilitate the realization of high-
energy lithium-ion batteries. However, the released oxygen species initiate materials surface …

Tailoring electronic structure to achieve maximum utilization of transition metal redox for high-entropy Na layered oxide cathodes

F Ding, H Wang, Q Zhang, L Zheng, H Guo… - Journal of the …, 2023 - ACS Publications
Charge compensation from cationic and anionic redox couples accompanying Na+ (de)
intercalation in layered oxide cathodes contributes to high specific capacity. However, the …

Restraining migration and dissolution of transition-metal-ions via functionalized separator for Li-rich Mn-based cathode with high-energy-density

Z Li, B Zhang, G Li, S Cao, C Guo, H Li, R Wang… - Journal of Energy …, 2023 - Elsevier
Lithium-rich manganese-based materials (LRMs) are promising cathode for high-energy-
density lithium-ion batteries due to their high capacity, low toxicity, and low cost. However …

Slab gliding, a hidden factor that induces irreversibility and redox asymmetry of lithium-rich layered oxide cathodes

JH Song, S Yu, B Kim, D Eum, J Cho, HY Jang… - Nature …, 2023 - nature.com
Lithium-rich layered oxides, despite their potential as high-energy-density cathode
materials, are impeded by electrochemical performance deterioration upon anionic redox …

Structure/Interface Coupling Effect for High‐Voltage LiCoO2 Cathodes

J Chen, H Chen, S Zhang, A Dai, T Li, Y Mei… - Advanced …, 2022 - Wiley Online Library
LiCoO2 (LCO) is widely applied in today's rechargeable battery markets for consumer
electronic devices. However, LCO operations at high voltage are hindered by accelerated …

Suppressing the dynamic oxygen evolution of sodium layered cathodes through synergistic surface dielectric polarization and bulk site‐selective co‐doping

X Xia, T Liu, C Cheng, H Li, T Yan, H Hu… - Advanced …, 2023 - Wiley Online Library
Utilizing anionic redox activity within layered oxide cathode materials represents a
transformational avenue for enabling high‐energy‐density rechargeable batteries. However …