Hydride transfer (HT) is a fundamental step in a wide range of reaction pathways, including
those mediated by dihydropyridinates (DHP− s). Coordination of ions directly to the pyridine …

Complexes of diamagnetic cations with radical anion ligands - IOPscience This site uses
cookies. By continuing to use this site you agree to our use of cookies. To find out more, see …

Non‐Innocent ligand complexes of aluminum are described in this Concept article,
beginning with a discussion of their synthesis, and then structural and electronic …

Redox-active ligands bring electron-and proton-transfer reactions to main-group
coordination chemistry. In this Forum Article, we demonstrate how ligand p K a values can …

N-alkylation and N-metallation of pyridine are explored herein to understand how metal-
ligand complexes can model NAD+ redox chemistry. Syntheses of substituted …

The relevance acquired by redox‐active ligands in modern catalysis stems from their facile
delivery and acceptance of electrons, either to the metal they coordinate to, or directly to an …

The novel class of gallium catalysts based on cationic gallium phthalocyanines (RPcGa+)
with SbF6–and Sb2F11–weakly coordinating anions was developed in order to using in the …

Conspectus Aluminum is the most abundant metal in the earth's crust at 8%, and it is also
widely available domestically in many countries worldwide, which ensures a stable supply …

Phenyl-bis (imino) pyridine (PhI2P) complexes,(PhI2P) ZnCl2 (1),(PhI2P−) ZnCl (2) and
(PhI2P−) Zn (py) Cl (3) were obtained with the I2P ligand in both the neutral and the one …

The reaction of Cl2GaH with a sodium salt of the dpp-Bian radical-anion (dpp-Bian•–) Na
(dpp-Bian= 1, 2-bis [(2, 6-diisopropylphenyl) imino] acenaphthene) affords paramagnetic …