Playing with organic radicals as building blocks for functional molecular materials

I Ratera, J Veciana - Chemical Society Reviews, 2012 - pubs.rsc.org
The literature has shown numerous contributions on the synthesis and physicochemical
properties of persistent organic radicals but there are a lesser number of reports about their …

Strategies towards single-chain magnets

HL Sun, ZM Wang, S Gao - Coordination Chemistry Reviews, 2010 - Elsevier
Single-chain magnets (SCM) are a novel class of molecular magnetic materials exhibiting
slow magnetic relaxation, which arises from large uniaxial type magnetic anisotropy, strong …

Synthesis of 3d Metallic Single-Molecule Magnets

G Aromí, EK Brechin - Single-molecule magnets and related phenomena, 2006 - Springer
The phenomenon of single-molecule magnetism was established in the early 1990s with the
cluster [Mn 12 O 12 (AcO) 16 (H 2 O) 4]. Since then, a large number of compounds …

Evidence for Single-Chain Magnet Behavior in a MnIII−NiII Chain Designed with High Spin Magnetic Units:  A Route to High Temperature Metastable Magnets

R Clérac, H Miyasaka, M Yamashita… - Journal of the American …, 2002 - ACS Publications
We herein present the synthesis, crystal structure, and magnetic properties of a new
heterometallic chain of MnIII and NiII ions,[Mn2 (saltmen) 2Ni (pao) 2 (py) 2](ClO4) 2 …

Slow dynamics of the magnetization in one-dimensional coordination polymers: single-chain magnets

H Miyasaka, M Julve, M Yamashita… - Inorganic chemistry, 2009 - ACS Publications
Slow relaxation of the magnetization (ie,“magnet-like” behavior) in materials composed of
magnetically isolated chains was observed for the first time in 2001. This type of behavior …

Single chain magnets: where to from here?

L Bogani, A Vindigni, R Sessoli… - Journal of Materials …, 2008 - pubs.rsc.org
Single chain magnets (SCMs) are an interesting class of molecular polymeric materials
displaying slow relaxation of the magnetization. They provide, at low temperatures, a …

Design of single chain magnets through cyanide-bearing six-coordinate complexes

R Lescouëzec, LM Toma, J Vaissermann… - Coordination chemistry …, 2005 - Elsevier
The design and preparation of stable cyanide-bearing six-coordinate complexes of formula
[MIII (L)(CN) x](x+ l− m)−(M= trivalent transition metal ion and L= polydentate blocking …

Single-Chain Magnet (NEt4)[Mn2(5-MeOsalen)2Fe(CN)6] Made of MnIII−FeIII−MnIII Trinuclear Single-Molecule Magnet with an ST = 9/2 Spin Ground …

M Ferbinteanu, H Miyasaka… - Journal of the …, 2005 - ACS Publications
The cyano-bridged trinuclear compound,(NEt4)[Mn2 (salmen) 2 (MeOH) 2Fe (CN)
6](1)(salmen2-= rac-N, N '-(1-methylethylene) bis (salicylideneiminate)), reported previously …

The coordination chemistry of pyridyl oximes

CJ Milios, TC Stamatatos, SP Perlepes - Polyhedron, 2006 - Elsevier
The coordination chemistry of pyridyl oximes is reviewed. Simple pyridyl oximes have the
general formula (py) C (R) NOH, where py is a pyridyl group (2-, 3-or 4-) attached to the …

Magnetic anisotropy of dysprosium (III) in a low-symmetry environment: a theoretical and experimental investigation

K Bernot, J Luzon, L Bogani, M Etienne… - Journal of the …, 2009 - ACS Publications
A mixed theoretical and experimental approach was used to determine the local magnetic
anisotropy of the dysprosium (III) ion in a low-symmetry environment. The susceptibility …