Conspectus Metathesis cyclopolymerization (CP) of α, ω-diynes is a powerful method to prepare functional polyacetylenes (PAs). PAs have long been studied due to their interesting …
Ruthenium alkoxymethylidene complexes have recently come into view as competent species for metathesis copolymerization reactions when coupled with appropriate …
Terminal alkynes display high reactivity toward Ru-carbene metathesis catalysts. However, the formation of a less reactive bulky carbene hinders their homopolymerization …
X Liu, F Liu, W Liu, H Gu - Polymer Reviews, 2021 - Taylor & Francis
Due to their unique physical and chemical features, dendronized polymers (DPs) have received increasing attention in various fields such as hierarchically structured materials …
C Kang, H Park, JK Lee, TL Choi - Journal of the American …, 2017 - ACS Publications
We demonstrate the first example of cascade polymerization by combining olefin metathesis and metallotropic 1, 3-shift reactions to form unique conjugated polyenynes. Rational design …
C Kang, K Jung, S Ahn, TL Choi - Journal of the American …, 2020 - ACS Publications
For decades, cyclopolymerization of α, ω-diyne derivatives has been an effective method to synthesize various soluble polyacetylenes containing five-to seven-membered rings in the …
H Jung, K Jung, M Hong, S Kwon, K Kim… - Journal of the …, 2018 - ACS Publications
Grubbs-type olefin metathesis catalysts are known to cyclopolymerize 1, 6-heptadiynes to afford conjugated polyenes containing five-or six-membered carbocycles. Although high …
C Kang, S Kwon, JC Sung, J Kim… - Journal of the …, 2018 - ACS Publications
On the basis of a combined experimental and computational study, a novel method for preparing fully conjugated polyenynes via cascade metathesis and metallotropy (M&M) …
N Kanbayashi, T Okamura… - Journal of the American …, 2019 - ACS Publications
Living cyclocopolymerization through the alternating insertion of an isocyanide and allene into palladium–carbon bond was developed based on the controlling the reactivity of the …