Conspectus Cyclometalated π-allyliridium-C, O-benzoate complexes discovered in the
Krische laboratory display unique amphiphilic properties, catalyzing both nucleophilic …

Herein, we report a synthesis of cyclohexanones bearing multi‐continuous stereocenters by
combining copper‐catalyzed asymmetric conjugate addition of dialkylzinc reagents to cyclic …

A stereodivergent synthesis of chiral β-lactams with contiguous tertiary/quaternary/tertiary
stereocenters has been achieved by a Cu/Ir-catalyzed three-component interrupted …

Construction of CN bond continues to be one part of the most significant goals in organic
chemistry because of the universal applications of amines in pharmaceuticals, materials and …

The installation of vicinal quaternary centers with absolute stereocontrol constitutes a
considerable challenge in organic synthesis. Herein, we introduce a novel [Cp* Ru (MeCN) …

Herein, we report an efficient kinetic resolution of alkyl allylic alcohols enabled by an iridium-
catalyzed enantioselective alkynylation of alkyl allylic alcohols with potassium …

An iridium-catalyzed stereoselective coupling of allylic ethers and alkynes to generate 3, 4-
substituted 1, 5-enynes is reported. Under optimized conditions, the coupling products are …

The limited nucleophilic character and the bidentate nature of unactivated nitroalkane
anions (nitronates) makes the corresponding alkylation and allylation procedures rather …

Cobalt/bisoxazolinephosphine-catalyzed allylic substitution of racemic allylic carbonates
with amines is a highly efficient method for the synthesis of allylic amines with exclusive …

New methods for preparation of chiral alkyl fluorides have been studied intensively in recent
years due to the favorable physicochemical and biological properties of those structures …