Laboratory spectroscopy techniques to enable observations of interstellar ion chemistry

BA McGuire, O Asvany, S Brünken… - Nature Reviews …, 2020 - nature.com
Molecular ions have long been considered key intermediates in the evolution of molecular
complexity in the interstellar medium. However, owing to their reactivity and transient nature …

Sub-Doppler frequency metrology in HD for tests of fundamental physics

FMJ Cozijn, P Dupré, EJ Salumbides, KSE Eikema… - Physical review …, 2018 - APS
Weak transitions in the (2, 0) overtone band of the hydrogen deuteride molecule at λ= 1.38 μ
m were measured in saturated absorption using the technique of noise-immune cavity …

OH+ and H2O+ absorption toward PKS 1830–211

S Muller, HSP Müller, JH Black, A Beelen… - Astronomy & …, 2016 - aanda.org
We report the detection of OH+ and H 2 O+ in the z= 0.89 absorber toward the lensed
quasar PKS 1830–211. The abundance ratio of OH+ and H 2 O+ is used to quantify the …

Formation of H2O+ and H3O+ cations in reactions of OH+ and H2O+ with H2: Experimental studies of the reaction rate coefficients from T= 15 to 300 K

TD Tran, S Rednyk, A Kovalenko… - The Astrophysical …, 2018 - iopscience.iop.org
OH+ and HO 2+ cations play a significant role in the chemistry of the cold interstellar
medium and hence their hydrogen abstraction reactions with H2 have to be included in ion …

Rotational state-dependent attachment of He atoms to cold molecular ions: An action spectroscopic scheme for rotational spectroscopy

S Brünken, L Kluge, A Stoffels, J Pérez-Ríos… - Journal of Molecular …, 2017 - Elsevier
We present a kinetics model description of a newly developed action spectroscopic method
for rotational spectroscopy based on rotational state-dependent three-body attachment of He …

Empirical line lists in the ExoMol database

Y Wang, J Tennyson, SN Yurchenko - Atoms, 2020 - mdpi.com
The ExoMol database aims to provide comprehensive molecular line lists for exoplanetary
and other hot atmospheres. The data are expanded by inclusion of empirically derived line …

Outflowing OH+ in Markarian 231: the ionization rate of the molecular gas

E González-Alfonso, J Fischer, S Bruderer… - The Astrophysical …, 2018 - iopscience.iop.org
The oxygen-bearing molecular ions OH+, H 2 O+, and H 3 O+ are key species that probe the
ionization rate of (partially) molecular gas that is ionized by X-rays and cosmic-rays …

High-resolution infrared spectroscopy of O2H+ in a cryogenic ion trap

H Kohguchi, P Jusko, KMT Yamada… - The Journal of …, 2018 - pubs.aip.org
The protonated oxygen molecule, O 2 H+, and its helium complex, He-O 2 H+, have been
investigated by vibrational action spectroscopy in a cryogenic 22-pole ion trap. For the He-O …

Fourier Transform Spectroscopy of the A3Π–X3Σ− Transition of OH+

JN Hodges, PF Bernath - The Astrophysical Journal, 2017 - iopscience.iop.org
The OH+ ion is of critical importance to the chemistry in the interstellar medium and is a
prerequisite for the generation of more complex chemical species. Submillimeter and …

Improved ultraviolet and infrared oscillator strengths for OH+

JN Hodges, DM Bittner, PF Bernath - The Astrophysical Journal, 2018 - iopscience.iop.org
Molecular ions are key reaction intermediates in the interstellar medium. OH+ plays a central
role in the formation of more complex chemical species and for estimating the cosmic ray …