Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups

Z Chen, B Wang, J Zhang, W Yu, Z Liu… - Organic Chemistry …, 2015 - pubs.rsc.org
Transition metal-catalyzed direct functionalization of C–H bonds is one of the key emerging
strategies that is currently attracting tremendous attention with the aim to provide alternative …

Dioxygen in polyoxometalate mediated reactions

IA Weinstock, RE Schreiber, R Neumann - Chemical reviews, 2017 - ACS Publications
In this review article, we consider the use of molecular oxygen in reactions mediated by
polyoxometalates. Polyoxometalates are anionic metal oxide clusters of a variety of …

Recent advances in positional-selective alkenylations: removable guidance for twofold C–H activation

W Ma, P Gandeepan, J Li, L Ackermann - Organic Chemistry Frontiers, 2017 - pubs.rsc.org
The transition metal-catalyzed transformation of otherwise inert C–H bonds into substituted
alkenes offers a versatile tool for the synthesis of value added olefinic molecules. Recent …

Nanostructured catalysts for organic transformations

LL Chng, N Erathodiyil, JY Ying - Accounts of chemical research, 2013 - ACS Publications
The development of green, sustainable and economical chemical processes is one of the
major challenges in chemistry. Besides the traditional need for efficient and selective …

Green strategies for transition metal-catalyzed C–H activation in molecular syntheses

U Dhawa, N Kaplaneris, L Ackermann - Organic Chemistry Frontiers, 2021 - pubs.rsc.org
Transition metal catalyzed C–H activation has surfaced as a powerful tool to improve the
efficacy of molecular synthesis. Last two decades have witnessed a considerable progress …

Heterogeneous catalytic approaches in C–H activation reactions

S Santoro, SI Kozhushkov, L Ackermann, L Vaccaro - Green Chemistry, 2016 - pubs.rsc.org
Despite the undisputed advances and progress in metal-catalyzed C–H functionalizations,
this atom-economical approach had thus far largely been developed with the aid of various …

Complex nanomaterials in catalysis for chemically significant applications: from synthesis and hydrocarbon processing to renewable energy applications

U Chadha, SK Selvaraj, H Ashokan… - … in Materials Science …, 2022 - Wiley Online Library
The world is rapidly changing, the resources are getting depleted, and the demand for
newer technologies and products is increasing. To keep up with these new advances, highly …

Catalytic C–H bond functionalisation chemistry: the case for quasi-heterogeneous catalysis

AJ Reay, IJS Fairlamb - Chemical Communications, 2015 - pubs.rsc.org
This feature article examines the potential of heterogeneous Pd species to mediate catalytic
C–H bond functionalisation processes employing suitable substrates (eg aromatic …

Heterogeneous C–H alkenylations in continuous-flow: oxidative palladium-catalysis in a biomass-derived reaction medium

F Ferlin, S Santoro, L Ackermann, L Vaccaro - Green Chemistry, 2017 - pubs.rsc.org
Herein we report the unprecedented Fujiwara–Moritani reaction catalysed by the
commercially available heterogeneous palladium catalyst Pd/C. The reaction works …

Amides as weak coordinating groups in proximal C–H bond activation

R Das, GS Kumar, M Kapur - European Journal of Organic …, 2017 - Wiley Online Library
Site selectivity is an inherent challenge in C–H functionalization reactions. The most
intensively sought‐after approaches have involved the employment of Lewis‐basic …