Cofactor-mimetic aerobic oxidation has conceptually merged with catalysis of syngas
reactions to form a wide range of Markovnikov-selective olefin radical …

Covering: July 2012 to June 2015. Previous review: Nat. Prod. Rep., 2013, 30, 869–915 The
structurally diverse imidazole-, oxazole-, and thiazole-containing secondary metabolites are …

An asymmetric approach for the first total synthesis of (−)-rhodomollanol A, a highly oxidized
diterpenoid, is described. The efficient synthetic strategy features three key …

Conspectus Natural product research originates from a desire to explore, understand, and
perturb biological function with atomic precision. To reach these goals at all, let alone …

A stereocontrolled total synthesis of the indole diterpenoid natural product paspaline is
described. Key steps include a highly diastereoselective enzymatic desymmetrization …

We report the total syntheses of two indole diterpenoid natural products, paspaline A and
emindole PB. Paspaline A is synthesized in a 9-step sequence from commercially available …

An enantioselective synthesis of the indole diterpenoid natural product paspaline is
disclosed. Critical to this approach was the implementation of stereoselective …

Herein, we report the enantioselective total synthesis of dysiherbols A, C, and D, a unique
group of 6/6/5/6/6 pentacyclic quinone/hydroquinone sesquiterpenes, featuring a photo …

We report here a concise and divergent enantioselective total synthesis of the revised
structures of marine anti-cancer sesquiterpene hydroquinone meroterpenoids (+) …

The first total synthesis of (−)‐hosieine A was accomplished and features an unprecedented
nitroso–ene cyclization to construct the 2‐azabicyclo [3.2. 1] octane ring system. Phosphine …