The preparation of well-defined functionalized polyolefins via coordination-insertion
polymerization method is a hot topic in polymer science. Late transition organometallic …

Transition metal-catalyzed olefin-polar monomer copolymerization holds great potential for
the synthesis of polar group-functionalized polyolefin materials. The dominant approach to …

Synthetic polymer chemistry endeavors to imitate the spatial and temporal control exhibited
within biological systems to obtain well-defined polymeric materials with unique structures …

Integrated catalysis is an emerging methodology that can streamline the multi-step synthesis
of complicated products in a single reaction vessel, achieving a high degree of control and …

Transition metal-catalyzed olefin polymerization dominates in the polyolefin field, and we
still have limited control over a catalyst's behavior. In addition to traditional steric and …

Controlling the chain growth process in non-living polymerization reactions is difficult
because chain termination typically occurs faster than the time it takes to apply an external …

A class of in situ-generated Ni-based multimetallic complexes based on a bisphosphine
phenoxide ligand (POP) was studied for ethylene-acrylate copolymerization. Starting from a …

Secondary metal cations, such as alkali and transition metal ions, have been shown to
enhance the catalytic performance of nickel and palladium olefin polymerization catalysts …

Metal-catalyzed coordination insertion polymerization is one of the most widely used
methods to prepare polyolefins, a broad class of polymers comprising a vast majority of the …

The secondary coordination interaction that differs from ligand steric and electronic
modification is an important tool to modulate the olefin polymerization process. In this …