Luminescent Complexes of Platinum, Iridium, and Coinage Metals Containing N-Heterocyclic Carbene Ligands: Design, Structural Diversity, and Photophysical …

H Amouri - Chemical Reviews, 2022 - ACS Publications
The employment of N-heterocyclic carbenes (NHCs) to design luminescent metal
compounds has been the focus of recent intense investigations because of the strong σ …

LNL-Carbazole Pincer Ligand: More than the Sum of Its Parts

G Kleinhans, AJ Karhu, H Boddaert, S Tanweer… - Chemical …, 2023 - ACS Publications
The utility of carbazole in photo-, electro-, and medicinal applications has ensured its
widespread use also as the backbone in tridentate pincer ligands. In this review, the aim is …

Tetradentate carbene–anilido boron complexes: highly fluorescent dyes with larger Stokes shifts than BODIPY analogues

J He, S Wang, XF Song, X Chang, C Zou… - Chemical …, 2024 - pubs.rsc.org
A new class of carbene–anilido boron complexes have been designed and synthesized.
The complexes show intense fluorescence with large Stokes shift because of their charge …

Selectivity in Competitive Csp2–Csp3 versus Csp3–Csp3 Reductive Eliminations at Pt(IV) Complexes: Experimental and Computational Approaches

F Niroomand Hosseini, SM Nabavizadeh… - …, 2021 - ACS Publications
Three classes of Pt (II) complexes of the types [PtMe2 (NHC)](NHC= 1, 1′-dimethyl-3, 3′-
methylenediimidazolin-2, 2′-diylidene),[PtMe2 (N^ N)](N^ N= 2, 2′-bipyridine, 1, 10 …

A Carbazole-bridged biscyclometalated diplatinum complex: synthesis, characterization, and dual-mode aggregation-enhanced phosphorescence

ZL Gong, K Tang, YW Zhong - Inorganic Chemistry, 2021 - ACS Publications
A cationic carbazole-bridged biscyclometalated diplatinum complex 4 has been synthesized
and characterized. Single-crystal X-ray analysis demonstrates that complex 4 displays a …

Nickel (II) Complex with the Bis (phenolate) Pincer N-Heterocyclic Carbene Ligand: Synthesis, Structure, and Properties

ZN Gafurov, IK Mikhailov, AA Kagilev… - Russian Journal of …, 2024 - Springer
The nickel (II) complex Ni (L) Py (I)(L is 1, 3-bis (3, 5-di-tert-butyl-2-phenolato)-5, 5-dimethyl-
(4, 6-dihydropyrimidin-2-ylidene)) containing the dianionic bonded N-heterocyclic carbene …

Recent progress on group 10 metal complexes of pincer ligands: from synthesis to activities and catalysis

KK Manar, P Ren - Advances in Organometallic Chemistry, 2021 - Elsevier
The pincer ligands have great interest due to their distinctive chelating nature toward the
metal center to form coordination complexes with high thermal stability. Organometallic …

Luminescent Platinum (II) Complexes with a Tridentate Caffeine‐Based NHC‐Pincer Ligand: Synthesis, Electrochemistry and Photophysics

O Bysewski, N Klosterhalfen, R Jordan… - European Journal of …, 2024 - Wiley Online Library
A strategy of “greening up” Pt (II) luminophores is presented. For this purpose, caffeine, as a
renewable alkaloid and precursor for an N‐heterocyclic carbene (NHC), is incorporated into …

Enhancing Charge Transfer in (BIMCA) Pt (II) Alkynyls through the Use of Substituted Boranes

T Liska, M Li, LM Cañada, S Yoon, TS Teets… - …, 2021 - ACS Publications
Organoboranes are commonly incorporated into ligands for luminescent molecules to
expand conjugation pathways and impart Lewis acidity. Here, we report on the use of …

Chemistry of vinylidene complexes—XXVII—new µ-vinylidene MnPt complexes with platinum-coordinated 1-adamantyl isocyanide ligand: spectroscopic, structural …

VV Verpekin, OS Chudin, AA Kondrasenko… - Transition Metal …, 2022 - Springer
New binuclear MnPt µ-vinylidene complexes Cp (CO) 2Mn (µ-C= CHPh) Pt (CN–Ad)(L)[L=
PPh3 (1a), P (OPri) 3 (2a)] bearing a terminal platinum-coordinated 1-adamantyl isocyanide …