Probing Dipole-Bound States Using Photodetachment Spectroscopy and Resonant Photoelectron Imaging of Cryogenically Cooled Anions
Molecular anions with polar neutral cores can support highly diffuse dipole-bound states
below their detachment thresholds due to the long-range charge–dipole interaction. Such …
below their detachment thresholds due to the long-range charge–dipole interaction. Such …
On the performance of second-order approximate coupled-cluster singles and doubles methods for non-valence anions
We investigate the capability of several variants of the second-order approximate coupled-
cluster singles and doubles (CC2) method to describe dipole-bound, quadrupole-bound …
cluster singles and doubles (CC2) method to describe dipole-bound, quadrupole-bound …
Observation of an excited dipole-bound state in a diatomic anion
We report the observation of σ-type and π-type excited dipole-bound states (DBSs) in
cryogenically cooled potassium iodide (KI) anions for the first time. Two DBSs were …
cryogenically cooled potassium iodide (KI) anions for the first time. Two DBSs were …
Probing the Strong Nonadiabatic Interactions in the Triazolyl Radical Using Photodetachment Spectroscopy and Resonant Photoelectron Imaging of Cryogenically …
Although the adiabatic potential energy surfaces defined by the Born-Oppenheimer
approximation are the cornerstones for understanding the electronic structure and …
approximation are the cornerstones for understanding the electronic structure and …
Velocity Map Imaging Spectroscopy of the Dipole-Bound State of CH2CN–: Implications for the Diffuse Interstellar Bands
BA Laws, ZD Levey, TW Schmidt… - Journal of the American …, 2021 - ACS Publications
Weakly bound anionic systems present a new domain for negative ion spectroscopy. Here
we report on a multifaceted study of the CH2CN–dipole-bound state, employing high …
we report on a multifaceted study of the CH2CN–dipole-bound state, employing high …
Dipole-bound state, photodetachment spectroscopy, and resonant photoelectron imaging of cryogenically-cooled 2-cyanopyrrolide
Valence-bound anions with polar neutral cores can have diffuse dipole-bound excited states
just below the electron detachment threshold. Because of the similarity in geometry and …
just below the electron detachment threshold. Because of the similarity in geometry and …
Observation of core-excited dipole-bound states
Polar molecules can bind an electron in a diffuse orbital due to the charge-dipole interaction.
Electronic excited states of polar molecules can also bind an electron to form core-excited …
Electronic excited states of polar molecules can also bind an electron to form core-excited …
Probing the electronic structure and spectroscopy of pyrrolyl and imidazolyl radicals using high-resolution photoelectron imaging of cryogenically cooled anions
High-resolution photoelectron imaging and photodetachment spectroscopy of cryogenically
cooled pyrrolide and imidazolide anions are used to probe the electronic structure and …
cooled pyrrolide and imidazolide anions are used to probe the electronic structure and …
Electron-Binding Dynamics of the Dipole-Bound State: Correlation Effect on the Autodetachment Dynamics
The nature of the electron-binding forces in the dipole-bound states (DBS) of anions is
interrogated through experimental and theoretical means by investigating the …
interrogated through experimental and theoretical means by investigating the …
[HTML][HTML] Observation of a dipole-bound excited state in 4-ethynylphenoxide and comparison with the quadrupole-bound excited state in the isoelectronic 4 …
Negative ions do not possess Rydberg states but can have Rydberg-like nonvalence excited
states near the electron detachment threshold, including dipole-bound states (DBSs) and …
states near the electron detachment threshold, including dipole-bound states (DBSs) and …