Alkenes and their related analogs are ideal starting materials for organic synthesis, and the
selective difunctionalization of alkenes, which allows the simultaneous introduction of two …

In the last few years, many reagents and protocols have been developed to allow for the
efficient fluorofunctionalization of a diverse set of scaffolds ranging from alkanes, alkenes …

The incorporation of trifluoromethyl groups into organic molecules such as agrochemicals
and pharmaceuticals has attracted a significant amount of interest because they will impact …

Semipinacol rearrangement has brought several elegant methods for the rapid synthesis of
various complex scaffolds and as a result, has been applied extensively in the total …

A catalytic charge transfer complex strategy that enabled difluoromethylation and
ethoxycarbonylmonofluoromethylation of enamides with phosphonium bromine salts has …

During the past decade, radical difluoromethylation has emerged as a powerful and
versatile tool for the incorporation of difluoromethyl into various organic compounds. These …

Abstract 1, 1, 2, 2‐Tetrafluoroethyl‐containing compounds are valuable structures due to
their unique physicochemical properties, which have increasing potential application in drug …

Reductive alkene difunctionalization is a valuable strategy for complex molecule synthesis,
but it typically requires a metal catalyst and stoichiometric amounts of a transition metal as …

An efficient and mild protocol for the visible light-induced radical cascade
difluoromethylation/cyclization of imidazoles with unactivated alkenes using easily …

Synthetic radicals have intrinsic power for cascading and multifunctional reactions to
construct diverse molecular scaffolds. In the previous review series, we covered 1, 2 …