Tuning metal–metal interactions for cooperative small molecule activation

Q Wang, SH Brooks, T Liu, NC Tomson - Chemical Communications, 2021 - pubs.rsc.org
Cluster complexes have attracted interest for decades due to their promise of drawing
analogies to metallic surfaces and metalloenzyme active sites, but only recently have …

Coordination polymers with exo-coordinated unsubstituted macrocycles: Structure, properties, future perspectives and design guidelines

T Balić, I Đilović - Coordination chemistry reviews, 2024 - Elsevier
This article overviews the structures and properties of coordination polymers (CPs) with
unsubstituted exo-macrocyclic ligands formed by coordinating inner macrocyclic ring donor …

Binuclear cobalt (II), nickel (II), copper (II) and palladium (II) complexes of a new Schiff-base as ligand: Synthesis, structural characterization, and antibacterial activity

B Geeta, K Shravankumar, PM Reddy… - … Acta Part A: Molecular …, 2010 - Elsevier
A binucleating new Schiff-base ligand with a phenylene spacer, afforded by the
condensation of glycyl–glycine and o-phthalaldehyde has been served as an octadentate …

Transition metal complexes of novel binuclear Schiff base derived from 3, 3′-diaminobenzidine: synthesis, characterization, thermal behavior, DFT, antimicrobial and …

VP Radha, S Chitra, S Jonekirubavathi… - Journal of …, 2020 - Taylor & Francis
A series of binuclear Co (II), Ni (II), Cu (II), and Zn (II) complexes were prepared with a novel
bidentate Schiff base ligand derived by condensation of 3, 3′-diaminobenzidine with …

[HTML][HTML] Isatin based macrocyclic Schiff base ligands as novel candidates for antimicrobial and antioxidant drug design: In vitro DNA binding and biological studies

AGB Dileepan, TD Prakash, AG Kumar… - … of Photochemistry and …, 2018 - Elsevier
In the present work, five macrocyclic compounds, C 18 H 12 N 2 O 4 (1), C 38 H 24 N 8 O 6
(1a), C 38 H 24 N 8 O 4 S 2 (1b), C 40 H 32 N 8 O 4 (2a) and C 48 H 32 N 8 O 4 (2b) have …

Transition-metal embedded carbon nitride monolayers: high-temperature ferromagnetism and half-metallicity

I Choudhuri, S Kumar, A Mahata, KS Rawat, B Pathak - Nanoscale, 2016 - pubs.rsc.org
High-temperature ferromagnetic materials with planar surfaces are promising candidates for
spintronics applications. Using state-of-the-art density functional theory (DFT) calculations …

Activation of bis (guanidinate) lanthanide alkyl and aryl complexes on elemental sulfur: synthesis and characterization of bis (guanidinate) lanthanide thiolates and …

Z Zhang, L Zhang, Y Li, L Hong, Z Chen… - Inorganic …, 2010 - ACS Publications
The treatment of [(Me3Si) 2NC (NCy) 2] 2Ln (μ-Cl) 2Li (THF) 2 with 1 equiv of BnK (Bn=
benzyl) in toluene affords [(Me3Si) 2NC (NCy) 2] 2LnBn [Ln= Er (1-Er), Y (1-Y)] in good …

Fifty Years of Inorganic Biomimetic Chemistry: From the Complexation of Single Metal Cations to Polynuclear Metal Complexes by Multidentate Thiolate Ligands

J Taut, JC Chambron, B Kersting - European Journal of …, 2023 - Wiley Online Library
This article covers 50 years of coordination chemistry of transition metal complexes and
metal‐sulfur aggregates involving thiolate‐incorporating ligands by reviewing selected …

Redox-Inactive Cation Assisted Direct Productions of Oxalic Acid and Dimethyl Oxalate via Oxidative CO Coupling Catalyzed by Coplanar Dicobalt Complexes

Y Xu, B Feng, S Li, X Li, H Fang - Organometallics, 2024 - ACS Publications
Metal–metal cooperativity is one of the most striking features of dinuclear complexes and
provides the cornerstone of many of their unique reactivities. In this research, an open-shell …

Metal-Free and Dicopper (II) Complexes of Schiff Base [2+ 2] Macrocycles Derived from 2, 2′-Iminobisbenzaldehyde: Syntheses, Structures, and Electrochemistry

SA Cameron, S Brooker - Inorganic chemistry, 2011 - ACS Publications
Three new bis-terdentate Schiff base [2+ 2] macrocycles (H2 L Et, H2 L Pr, and H2 L Bu)
have been prepared in high yields by 1: 1 condensation of 2, 2′-iminobisbenzaldehyde …