Frustrated Lewis pair chemistry: development and perspectives

DW Stephan, G Erker - Angewandte Chemie International …, 2015 - Wiley Online Library
Abstract Frustrated Lewis pairs (FLPs) are combinations of Lewis acids and Lewis bases in
solution that are deterred from strong adduct formation by steric and/or electronic factors …

FLP catalysis: main group hydrogenations of organic unsaturated substrates

J Lam, KM Szkop, E Mosaferi… - Chemical Society Reviews, 2019 - pubs.rsc.org
This article is focused on recent developments in main group mediated hydrogenation
chemistry and catalysis using “frustrated Lewis pairs”(FLPs). The broading range of …

Frustrated lewis pairs

DW Stephan - Journal of the American Chemical Society, 2015 - ACS Publications
The articulation of the notion of “frustrated Lewis pairs”(FLPs), which emerged from the
discovery that H2 can be reversibly activated by combinations of sterically encumbered …

Frustrated Lewis pairs: from concept to catalysis

DW Stephan - Accounts of chemical research, 2015 - ACS Publications
Conspectus Frustrated Lewis pair (FLP) chemistry has emerged in the past decade as a
strategy that enables main-group compounds to activate small molecules. This concept is …

Asymmetric catalysis with FLPs

X Feng, W Meng, H Du - Chemical Society Reviews, 2023 - pubs.rsc.org
Chiral catalysts play a crucial role in the realm of asymmetric catalysis. Since their
breakthrough discovery in 2006, chiral frustrated Lewis pairs (FLPs) have risen as a novel …

Chemie frustrierter Lewis‐Paare: Entwicklung und Perspektiven

DW Stephan, G Erker - Angewandte Chemie, 2015 - Wiley Online Library
Abstract Der Begriff “frustrierte Lewis‐Paare”(FLPs) bezeichnet Kombinationen von Lewis‐
Säuren und Lewis‐Basen in Lösung, die aufgrund sterischer oder elektronischer Faktoren …

Frustrated Lewis pairs catalyzed asymmetric metal-free hydrogenations and hydrosilylations

W Meng, X Feng, H Du - Accounts of chemical research, 2018 - ACS Publications
Conspectus The use of frustrated Lewis pairs is an extremely important approach to metal-
free hydrogenations. In contrast to the rapid growth of catalytic reactions, asymmetric …

Recent advances in catalytic sequential reactions involving hydroelement addition to carbon–carbon multiple bonds

X Zeng - Chemical Reviews, 2013 - ACS Publications
Sequential reactions, through the incorporation of several distinct transformations into one
single sequence, are one of the most powerful synthetic tools in modern organic chemistry …

Metal‐free hydrogenation of unsaturated hydrocarbons employing molecular hydrogen

J Paradies - Angewandte Chemie International Edition, 2014 - Wiley Online Library
The metal‐free activation of hydrogen by frustrated Lewis pairs (FLPs) is a valuable method
for the hydrogenation of polarized unsaturated molecules ranging from imines, enamines …

Metal‐free Catalytic Olefin Hydrogenation: Low‐Temperature H2 Activation by Frustrated Lewis Pairs

L Greb, P Oña‐Burgos, B Schirmer… - Angewandte Chemie …, 2012 - Wiley Online Library
The hydrogenation of double bonds is one of the most fundamental transformations [1] in
organic chemistry, and has numerous applications in the commodity chemical …