Asymmetric catalysis at chiral metal surfaces

T Mallat, E Orglmeister, A Baiker - Chemical Reviews, 2007 - ACS Publications
The remarkable development in homogeneous enantioselective catalysis reflected by the
Nobel prizes in 2001 awarded to Sharpless, Noyori, and Knowles has further spurred the …

Transition metal-based bimetallic catalysts for the chemoselective hydrogenation of furfuraldehyde

V Vetere, AB Merlo, JF Ruggera… - Journal of the Brazilian …, 2010 - SciELO Brasil
In this work, the liquid-phase chemoselective hydrogenation of furfural was studied,
employing Pt, Rh and Ni-based catalysts. Bimetallic systems, containing different amounts of …

Chiral metal nanoparticles for asymmetric catalysis

T Yasukawa, S Kobayashi - Nanoparticles in Catalysis, 2020 - Springer
Metal nanoparticles modified by chiral ligands or chiral polymers, called as “chiral metal
nanoparticles,” are promising catalysts for asymmetric organic transformations. In this …

[图书][B] Chiral nanomaterials: preparation, properties and applications

Z Tang - 2017 - books.google.com
Thorough and up-to-date, this book presents recent developments in this exciting research
field. To begin with, the text covers the fabrication of chiral nanomaterials via various …

Liquid-phase furfural hydrogenation employing silica-supported PtSn and PtGe catalysts prepared using surface organometallic chemistry on metals techniques

AB Merlo, V Vetere, JM Ramallo-López… - Reaction Kinetics …, 2011 - akjournals.com
Platinum–germanium and platinum–tin catalysts supported on silica, containing different
amounts of Sn and Ge, were synthesized using the surface organometallic chemistry on …

Chemoselective hydrogenation of aromatic ketones with Pt-based heterogeneous catalysts. Substituent effects

V Vetere, AB Merlo, ML Casella - Applied Catalysis A: General, 2015 - Elsevier
Catalytic reduction of aromatic ketones is an interesting reaction that leads to the obtaining
of alcohols. Some of these alcohols are employed as intermediaries to produce chemical …

Tuning enantioselectivity in asymmetric hydrogenation of acetophenone and its derivatives via confinement effect over free-standing mesoporous palladium network …

Y Wang, N Su, L Ye, Y Ren, X Chen, Y Du, Z Li, B Yue… - Journal of catalysis, 2014 - Elsevier
The confinement effect on enantioselective hydrogenation of acetophenone and its
derivatives over free-standing mesoporous Pd network catalysts was systematically studied …

Stereoselective biocatalytic hydride transfer to substituted acetophenones by the yeast Metschnikowia koreensis

A Singh, Y Chisti, UC Banerjee - Process Biochemistry, 2012 - Elsevier
Freely suspended and variously entrapped viable cells of the yeast Metschnikowia
koreensis were examined for the asymmetric reduction of prochiral acetophenone. A ketone …

Effect of solvent in the hydrogenation of acetophenone catalyzed by Pd/S-DVB

T Bereta, E Mieczyńska, S Ronka, W Tylus… - New Journal of …, 2021 - pubs.rsc.org
A solvent effect was found in the hydrogenation of acetophenone catalyzed by a new Pd/S-
DVB catalyst, immobilized on a styrene (S)/divinylbenzene (DVB) copolymer containing …

Direct synthesis of in-situ chirally modified palladium nanocrystals without capping agents and their application in heterogeneous enantioselective hydrogenations

X Gao, X Chen, ZH Li, H He - ACS Catalysis, 2019 - ACS Publications
Shape-controlled metal nanocrystals possess the advantages of specific atomic
arrangement on the surface and uniform size, which can act as ideal model catalysts for …