The objective of this review is to update a previous one (published in 1999) on the kinetics
and mechanism of the reactions of thioesters, thiocarbonates and analogous thiocarbonyl …

The specific rates of solvolyis of methyl chloroformate are very well correlated by the
extended Grunwald–Winstein equation over a wide range of solvents; the pathway is …

Application of the extended Grunwald-Winstein equation to solvolyses of n‑propyl
chloroformate in a variety of pure and binary solvents indicates an addition-elimination …

Additional specific rates of solvolysis are determined for phenyl chloroformate. These values
are combined with literature values to give a total of 49 data points, which are used within …

Il existe une similitude remarquable entre les vitesses spécifiques de solvolyse du
chlorothionoformate de phényle (PhOCSCl) et celle rapportée antérieurement pour le …

The specific rates of solvolysis of methanesulfonic anhydride have been measured
conductometrically at− 10° C in 41 solvents. Use of the extended Grunwald–Winstein …

Specific rates of solvolysis at 25° C for isopropyl chloroformate (1) in 24 solvents of widely
varying nucleophilicity and ionizing power, plus literature values for studies in water and …

Hydrolyses of acid derivatives (eg, carboxylic acid chlorides and fluorides, fluoro-and
chloroformates, sulfonyl chlorides, phosphorochloridates, anhydrides) exhibit pseudo-first …

The specific rates of solvolysis of neopentyl chloroformate (1) have been determined in 21
pure and binary solvents at 45.0° C. In most solvents the values are essentially identical to …

On a déterminé de nouvelles vitesses spécifiques de solvolyse pour le chlorure d'acétyle et
le chlorure de diphénylacétyle. Les valeurs ainsi déterminées ont été combinées à celles …