The unique properties of natural tetrapyrrolic compounds have inspired the rapid growth of
research interest in the design and synthesis of artificial porphyrinoids and their metal …

Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …

Herein we report the synthesis and characterization of a dinuclear TbIII single-molecule
magnet (SMM) with two [TbPc2] 0 units connected via a fused-phthalocyaninato ligand. The …

Two sets of isostructural Ln (III) mononuclear complexes,[Ln (NO3) 3 (18-crown-6)](Ln= Ce
(1), Pr (2), and Nd (3)) and [Ln (NO3) 3 (1, 10-diaza-18-crown-6)](Ln= Ce (4), Pr (5), and Nd …

Substantial efforts have been made to design and investigate new approaches for high-
performance nonlinear optical (NLO) materials. Herein, we report polaron formation in …

Recent studies have highlighted the importance of organic ligands in the field of molecular
spintronics, via which delocalized electron-spin density can mediate magnetic coupling to …

Double-and triple-decker lanthanide phthalocyaninates exhibit unique physical-chemical
properties, particularly single-molecule magnetism. Among other factors, the magnetic …

By using density functional theory (PBE functional and Grimme's dispersion correction) we
studied how a stepwise addition of 4f electrons influences the geometries and electronic …

Ligand paramagnetic NMR (pNMR) chemical shifts of the 5f1 complexes UO2 (CO3) 35–and
NpO2 (CO3) 34–, and of the 5f2 complexes PuO2 (CO3) 34–and (C5H5) 3UCH3 are …

Two homoleptic copper (II) complexes [Cu (L1) 2] and [Cu (L2) 2] with anionic redox‐active
ligands were synthesised, one with urea azine (L1) and the other with thio‐urea azine (L2) …