Transition metal species readily capture and react with CO as the metal can act both as an
acceptor and donor of electron density. In contrast, such a situation is less common in the …

The conversion of CO2 into multicarbon (C2+) compounds by reductive homocoupling offers
the possibility to transform renewable energy into chemical energy carriers and thereby …

The usage of carbon monoxide (CO) as a C1 feedstock for carbonylation has been an
important subject of numerous studies for over a century. The chemistry in this field has …

Since the seminal report on Mg in the+ I oxidation state in 2007, low-valent complexes
featuring a MgI–MgI bond developed from trophy molecules to state-of-the-art reducing …

Sodium reduction of [{SiNDipp} Mg][{SiNDipp}={CH2SiMe2N (Dipp)} 2; Dipp= 2, 6-i-
Pr2C6H3] provides the Mg (I) species,[{SiNDipp} MgNa] 2, in which the long Mg–Mg bond (> …

Homologation of carbon monoxide is central to the heterogeneous Fischer–Tropsch process
for the production of hydrocarbon fuels. C–C bond formation has been modeled by …

An extremely bulky xanthene bridged diamide ligand (TCHPNON= 4, 5-bis (2, 4, 6-
tricyclohexylanilido)-2, 7-diethyl-9, 9-dimethyl-xanthene) has been developed and used to …

The synthesis, characterisation and reactivity of two isostructural anionic magnesium and
calcium complexes is reported. By X‐ray and neutron diffraction techniques, the anionic …

Lithium dicyclohexylamide (Cy2NLi) reacts with syn-gas or CO to generate transient
intermediates with carbene character, which are capable of reacting further with CO or H2 …

Perfluoroalkyl substances (PFAS) are pervasive in the environment. The largest single use
material within the PFAS compound class is poly (tetrafluoroethylene)(PTFE), a robust and …