Nickel-catalyzed reactions have attracted more and more attention. A variety of
transformations of organic compounds have been achieved through single-electron or two …

Ni-catalyzed enantioselective hydrofunctionalizations of conjugated dienes are particularly
demanding reactions to devise because they require not only addressing the inherent …

The straightforward construction of stereogenic centers bearing unprotected functional
groups, as in nature, has been a persistent pursuit in synthetic chemistry. Abundant …

Transition metal-catalyzed asymmetric hydrofunctionalizations of unsaturated bonds via π-
ƞ3 substitution have emerged as a reliable method to construct stereogenic centers, and …

As an advance in hydrofunctionalization, we herein report that alcohols add to 1, 3-dienes
with high regio-and enantioselectivity. Using Ni-DuPhos, we access enantioenriched allylic …

Transition‐metal‐catalyzed asymmetric carbon− carbon bond formation to forge
phosphonates with an α‐chiral carbon center through C (sp3)− C (sp3) and C (sp2)− C (sp3) …

The catalytic asymmetric synthesis of P-stereogenic phosphines is an efficient strategy to
access structurally diverse chiral phosphines that could serve as organocatalysts and …

Abstract Electronically matched nucleophilic 1, 6‐conjugate addition has been well studied
and widely applied in synthetic areas. In contrast, nucleophilic 1, 5‐conjugate addition …

A Cu/CPA co‐catalytic system has been developed for achieving the direct
hydrophosphinylation of alkynes with phosphine oxides in delivering novel axially chiral …

Different from classical allylic substitutions that require a vicinal leaving group, an olefin
bearing a remote leaving group is scarcely viewed as a potential allylation substrate. Herein …