Polymers without petrochemicals: sustainable routes to conventional monomers

G Hayes, M Laurel, D MacKinnon, T Zhao… - Chemical …, 2022 - ACS Publications
Access to a wide range of plastic materials has been rationalized by the increased demand
from growing populations and the development of high-throughput production systems …

NHCs in main group chemistry

V Nesterov, D Reiter, P Bag, P Frisch, R Holzner… - Chemical …, 2018 - ACS Publications
Since the discovery of the first stable N-heterocyclic carbene (NHC) in the beginning of the
1990s, these divalent carbon species have become a common and available class of …

Chemically recyclable polymers: a circular economy approach to sustainability

M Hong, EYX Chen - Green Chemistry, 2017 - pubs.rsc.org
The current practices in the generation and disposal of synthetic polymers are largely
unsustainable. As part of the solution, the development of biodegradable polymers, which …

The broadening reach of frustrated Lewis pair chemistry

DW Stephan - Science, 2016 - science.org
BACKGROUND Since the work of Sabatier 100 year ago, chemists have turned almost
exclusively to metals to activate H2 by weakening or cleaving its central bond. This …

Frustrated Lewis pair chemistry: development and perspectives

DW Stephan, G Erker - Angewandte Chemie International …, 2015 - Wiley Online Library
Abstract Frustrated Lewis pairs (FLPs) are combinations of Lewis acids and Lewis bases in
solution that are deterred from strong adduct formation by steric and/or electronic factors …

Alternative monomers based on lignocellulose and their use for polymer production

I Delidovich, PJC Hausoul, L Deng… - Chemical …, 2016 - ACS Publications
Polymeric materials play a key role in modern industry. Owing to outstanding and very
versatile properties of polymers, they have rather quickly occupied the great niche of …

Frustrated lewis pairs

DW Stephan - Journal of the American Chemical Society, 2015 - ACS Publications
The articulation of the notion of “frustrated Lewis pairs”(FLPs), which emerged from the
discovery that H2 can be reversibly activated by combinations of sterically encumbered …

New directions for frustrated Lewis pair chemistry

AR Jupp, DW Stephan - Trends in Chemistry, 2019 - cell.com
The concerted action of a Lewis acid and base can activate H 2 and other small molecules.
Such frustrated Lewis pairs (FLPs) have garnered much attention and prompted many …

Recent trends in catalytic polymerizations

DJ Walsh, MG Hyatt, SA Miller, D Guironnet - ACS Catalysis, 2019 - ACS Publications
Polymers have become one of the largest and most important materials we use in daily life.
Their popularity has stemmed from their wide range of material properties combined with …

Recyclable cyclic bio-based acrylic polymer via pairwise monomer enchainment by a trifunctional Lewis pair

Y Song, J He, Y Zhang, RA Gilsdorf, EYX Chen - Nature Chemistry, 2023 - nature.com
The existing catalyst/initiator systems and methodologies used for the synthesis of polymers
can access only a few cyclic polymers composed entirely of a single monomer type, and the …