Vibrational control of bimolecular reactions with methane by mode, bond, and stereo selectivity

K Liu - Annual review of physical chemistry, 2016 - annualreviews.org
Vibrational motions of a polyatomic molecule are multifold and can be as simple as stretches
or bends or as complex as concerted motions of many atoms. Different modes of excitation …

Crossed beam polyatomic reaction dynamics: recent advances and new insights

H Pan, K Liu, A Caracciolo… - Chemical Society Reviews, 2017 - pubs.rsc.org
Over the past ten years or so, great advances in our understanding of the dynamics of
elementary (bimolecular) polyatomic reactions in the gas-phase have occurred. This has …

Stereodynamical control of the H + HD → H2 + D reaction through HD reagent alignment

Y Wang, J Huang, W Wang, T Du, Y Xie, Y Ma, C Xiao… - Science, 2023 - science.org
Prealigning nonpolar reacting molecules leads to large stereodynamical effects because of
their weak steering interaction en route to the reaction barrier. However, experimental …

Control of chemical reactivity by transition-state and beyond

H Guo, K Liu - Chemical science, 2016 - pubs.rsc.org
It has been long established that the transition state for an activated reaction controls the
overall reactivity, serving as the bottleneck for reaction flux. However, the role of the …

Quantum stereodynamics of cold molecular collisions

N Balakrishnan, PG Jambrina, JFE Croft… - Chemical …, 2024 - pubs.rsc.org
Advances in quantum state preparations combined with molecular cooling and trapping
technologies have enabled unprecedented control of molecular collision dynamics. This …

Role of Low Energy Resonances in the Stereodynamics of Cold He + D2 Collisions

PG Jambrina, M Morita, JFE Croft, FJ Aoiz… - The Journal of …, 2022 - ACS Publications
In recent experiments using the Stark-induced adiabatic Raman passage technique, Zhou et
al.(J. Chem. Phys. 2021, 154, 104309; Science 2021, 374, 960–964) measured the …

Imaging quantum stereodynamics through Fraunhofer scattering of NO radicals with rare-gas atoms

J Onvlee, SDS Gordon, SN Vogels, T Auth, T Karman… - Nature …, 2017 - nature.com
Stereodynamics describes how the vector properties of molecules, such as the directions in
which they move and the axes about which they rotate, affect the probabilities (or cross …

Rotational mode specificity in the Cl+ CHD3→ HCl+ CD3 reaction

R Liu, F Wang, B Jiang, G Czakó, M Yang… - The Journal of …, 2014 - pubs.aip.org
Rotational mode specificity in the Cl + CHD3 → HCl + CD3 reaction | The Journal of Chemical
Physics | AIP Publishing Skip to Main Content Umbrella Alt Text Umbrella Alt Text Close …

Stereodynamical Control of Cold Collisions between Two Aligned Molecules

PG Jambrina, JFE Croft, J Zuo, H Guo… - Physical Review Letters, 2023 - APS
Resonant scattering of optically state-prepared and aligned molecules in the cold regime
allows the most detailed interrogation and control of bimolecular collisions. This technique …

Taming molecular collisions using electric and magnetic fields

M Brouard, DH Parker… - Chemical Society …, 2014 - pubs.rsc.org
The motion of molecules that possess a permanent electric or magnetic dipole moment can
be manipulated using electric or magnetic fields. Various devices have been developed …