Polyoxometalates (POMs) are interesting clusters that attracted great attention due to their
remarkable structures and intriguing applications. The incorporation of POMs into crystalline …

Polyoxometalate-based open frameworks (POM-OFs) are extended architectures
incorporating metal-oxide cluster units and comprise an emergent family of materials with a …

Inorganic oxide materials are used in semiconductor electronics, ion exchange, catalysis,
coatings, gas sensors and as separation materials. Although their synthesis is well …

Polyoxometalates (POMs) are an intriguing class of compounds that have been extensively
studied due to their unique structures and diverse properties. In the past years, the synthesis …

Crystallization at the solid–liquid interface is difficult to spectroscopically observe and
therefore challenging to understand and ultimately control at the molecular level. The Ce70 …

Purely inorganic porous frameworks using catalytically active [MnV13O38] 7− clusters as
nodes and rare earth ions as linkers have been successfully prepared. The POM-based …

We describe why the cyclic heteropolyanion [P8W48O184] 40–(abbreviated as {P8W48}) is
an ideal building block for the construction of intrinsically porous framework materials by …

Superatoms are nanometer-sized molecules or particles that form ordered lattices,
mimicking their atomic counterparts. Hierarchical assembly of superatoms gives rise to …

Hydrothermal reaction of a macrocyclic inorganic POM cavitand Li17 (NH4) 21H2
[P8W48O184] with [Pt (H2O) 2 (OH) 4] results in coordination of up to six {Pt (H2O) x (OH) 4 …

A series of organic–inorganic hybrid compounds built from Keggin and Wells–Dawson
polyoxometalates and TM-trz complexes (Htrz= 1, 2, 4-triazole) were obtained at different pH …